[copper(II)(5-(bis((pyridin-2-yl)methyl)amino)pentanoate)]*MeOH | 1229445-48-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [copper(II)(5-(bis((pyridin-2-yl)methyl)amino)pentanoate)]*MeOH
• CAS: 1229445-48-0
• 化学式: CH₄O*C₁₇H₂₀CuN₄O₅
• 分子量: 455.958
• InChiKey: OKNZKOXRQIVKBN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 5-[bis(pyridin-2-yl)methyl]amino-1-pentanoic acid 、 copper(II) nitrate trihydrate 以 甲醇 、 水 为溶剂， 以54%的产率得到[copper(II)(5-(bis((pyridin-2-yl)methyl)amino)pentanoate)]*MeOH
  参考文献：
  名称：

  Coordination polymers of Cu(II) and Cd(II) with bifunctional chelates of the type dipicolylamino-alkylcarboxylate, (NC5H4CH2)2N(CH2)nCO2H (n = 1, 2, 3 and 4)

  摘要：

  A series of bifunctional chelates of the type dipicolylamino-alkylcarboxylate (NC5H4CH2)(2)N(CH2)(n)CO2H (n = 1-4; HL1-HL4, respectively) has been prepared. Reactions of the ligands in aqueous methanol/N,N-dimethylformamide with the appropriate Cu(II) salts yielded the compounds [CuL1](NO3)center dot H2O (1 center dot H2O), [CuL2(H2O)]BF4 center dot H2O (2 center dot H2O), [Cu(HL3)(SO4)](2) (3) and [CuL4(NO3)]center dot MeOH (4 center dot MeOH). While compounds 1, 2 and 4 are one-dimensional, the detailed connectivities within the chains are quite distinct, depending on factors such as alkyl chain length and ligation of aqua ligands or anionic components. In contrast to 1, 2 and 4, the structure of 3 is molecular, a binuclear assembly of edge-sharing Cu(II) '4+2' distorted octahedra The Cd(II) species, [{CdL2}(2)(SO4)]center dot 4H(2)O (5 center dot 4H(2)O), prepared from HL2 and CdSO4 center dot nH(2)O in aqueous methanol/N,N-dimethylformamide, is two-dimensional, with a network constructed from binuclear units of seven coordinate Cd(II), {CdL2}(2)(2+), linked through bridging SO42+ groups to produce an assembly of linked hexagonal rings [{CdL2}(2)(SO4)](6). (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.01.006