[Zn(CH3COO)2(pyridine-4-amidoxime)2] | 1609239-86-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Zn(CH3COO)2(pyridine-4-amidoxime)2]
• 英文别名: [Zn(CH₃COO)₂(pyridine-4-amidoxime)₂]；[Zn(CH₃COO)₂(4-pyamo)₂]
• CAS: 1609239-86-2
• 化学式: C₁₆H₂₀N₆O₆Zn
• 分子量: 457.761
• InChiKey: ODSITXPFXPRFIX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-吡啶基偕胺肟 、 zinc(II) acetate dihydrate 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 0.33h， 以0.23%的产率得到[Zn(CH3COO)2(pyridine-4-amidoxime)2]
  参考文献：
  名称：

  Preparation, structural characterization and luminescence studies of mono- and binuclear Zn(II) and Cd(II) acetates with pyridine-4-aldoxime and pyridine-4-amidoxime ligands

  摘要：

  Mono- and binuclear Zn(II)/Cd(II) pyridine-4-aldoxime and pyridine-4-amidoxime complexes, [Zn(CH3COO)(2)(4-pYao)(2)] (1), [Zn(CH3COO)(2)(4-Pyamo)(2)] (2), [Cd-2(CH3COO)(4)(4-Pyao)(4)]center dot 4H(2)O (3), [Cd-2(CH3COO)(4)(4-pyamo)(4)]center dot 2DMF (4) and [Cd(CH3COO)(2)(4-Pyao)(3)]center dot 3H(2)O (5) (4-Pyao = pyridine-4-aldoxime; 4-pyamo = pyridine-4-amidoxime), were synthesized and characterized by elemental analysis, IR spectroscopy and X-ray structure determination. The mononuclear compounds 1 and 2 contain two, while compound 5 contains three neutral pyridine-4-aldoxime ligands coordinated to the metal center through the N-pyridyl atom. The acetate anions coordinate in monodentate (1, 2), bidentate (3-5) and bidentate-bridging (3,4) modes. Compounds 2, 3 and 5 display blue luminescence upon excitation with ultraviolet light. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2014.03.008