5,5'-di(thiazol-5-yl)-2,2'-bithiophene | 1256960-80-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 双噻吩和低聚噻吩
• 英文名称: 5,5'-di(thiazol-5-yl)-2,2'-bithiophene
• 英文别名: 5-[5-[5-(1,3-Thiazol-5-yl)thiophen-2-yl]thiophen-2-yl]-1,3-thiazole
• CAS: 1256960-80-1
• 化学式: C₁₄H₈N₂S₄
• 分子量: 332.495
• InChiKey: FUKXHCXZYMGWHP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  139
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  5,5'-di(thiazol-5-yl)-2,2'-bithiophene 、 三(五氟苯基)硼烷 以 甲苯 为溶剂， 以83%的产率得到5,5'-di(thiazol-5-yl)-2,2'-bithiophene-bis[tris(pentafluorophenyl)borane]adduct
  参考文献：
  名称：

  Electronic Tuning of Thiazolyl-Capped π-Conjugated Compounds via a Coordination/Cyclization Protocol with B(C₆F₅)₃

  摘要：

  Electronic tuning of thiazolyl-capped pi-conjugated systems via a coordination/cyclization protocol with B(C6F5)(3) effectively enhances an electron-accepting character giving rise to lower reduction potentials and increases thermal stability.

  DOI：

  10.1021/ol102282x
• 作为产物：
  描述：

  5,5'-bis[2-(triisopropylsilyl)thiazol-5-yl]-2,2'-bithiophene 在 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 反应 1.5h， 以84%的产率得到5,5'-di(thiazol-5-yl)-2,2'-bithiophene
  参考文献：
  名称：

  Electronic Tuning of Thiazolyl-Capped π-Conjugated Compounds via a Coordination/Cyclization Protocol with B(C₆F₅)₃

  摘要：

  Electronic tuning of thiazolyl-capped pi-conjugated systems via a coordination/cyclization protocol with B(C6F5)(3) effectively enhances an electron-accepting character giving rise to lower reduction potentials and increases thermal stability.

  DOI：

  10.1021/ol102282x

文献信息

• ORGANIC SEMICONDUCTOR ELEMENT AND METHOD FOR PRODUCING SAME, COMPOUND, ORGANIC SEMICONDUCTOR COMPOSITION AND ORGANIC SEMICONDUCTOR FILM AND METHOD FOR PRODUCING SAME
  申请人：FUJIFILM Corporation

  公开号：EP3258513A1

  公开（公告）日：2017-12-20

  Objects of the present invention are to provide an organic semiconductor element in which carrier mobility is high, variation of mobility is suppressed, and temporal stability under high temperature and high humidity is excellent, and a manufacturing method thereof, to provide a novel compound suitable for an organic semiconductor, and to provide an organic semiconductor film in which mobility is high, variation of mobility is suppressed, and temporal stability under high temperature and high humidity is excellent, a manufacturing method thereof, and an organic semiconductor composition that can suitably form the organic semiconductor film. The organic semiconductor element according to the present invention is an organic semiconductor layer containing a compound having a constitutional repeating unit represented by Formula 1 and having a molecular weight of 2,000 or greater.         (̵D-A)̵     (1)

  本发明的目的是提供一种载流子迁移率高、迁移率变化受抑制、高温高湿条件下的时间稳定性优异的有机半导体元件及其制造方法，提供一种适用于有机半导体的新型化合物，并提供一种迁移率高、迁移率变化受抑制、高温高湿条件下的时间稳定性优异的有机半导体薄膜及其制造方法，以及一种可适当形成该有机半导体薄膜的有机半导体组合物。 根据本发明的有机半导体元件是一种有机半导体层，其中含有一种化合物，该化合物具有由式 1 表示的构型重复单元，且分子量大于等于 2,000。 (̵D-A)̵ (1)