7-octene-1-sulfonic acid | 923279-54-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: 7-octene-1-sulfonic acid
• 英文别名: Oct-7-ene-1-sulfonic acid
• CAS: 923279-54-3
• 化学式: C₈H₁₆O₃S
• 分子量: 192.279
• InChiKey: OVCNPZONSFJKRX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  62.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  7-octene-1-sulfonic acid 在 N,N-二异丙基乙胺 、 Methanaminium,N-[(dimethylamino)(3H-1,2,3-triazolo[4,5-b]pyridin-3-yloxy)methylene]-N-methyl-, hexafluorophosphate(1-) 、 lithium hydroxide 、 三氯氧磷 作用下， 以 四氢呋喃 、 甲醇 、 二氯甲烷 、 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 methyl (1R,2S)-1-((2S,4S)-4-(((4-bromophenyl)sulfonyl)oxy)-1-(oct-7-en-1-ylsulfonyl)pyrrolidine-2-carboxamido)-2-vinylcyclopropane-1-carboxylate
  参考文献：
  名称：

  Novel, sulfonamide linked inhibitors of the hepatitis C virus NS3 protease

  摘要：

  A sulfonamide replacement of the P2-P3 amide bond in the context of macrocyclic HCV NS3 protease inhibitors was investigated. These analogs displayed good inhibitory potency in the absence of any P3 capping group. The synthesis and preliminary SAR are described. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmcl.2013.12.060
• 作为产物：
  描述：

  8-溴-1-辛烯 在 sodium sulfite 作用下， 生成 7-octene-1-sulfonic acid
  参考文献：
  名称：

  Novel, sulfonamide linked inhibitors of the hepatitis C virus NS3 protease

  摘要：

  A sulfonamide replacement of the P2-P3 amide bond in the context of macrocyclic HCV NS3 protease inhibitors was investigated. These analogs displayed good inhibitory potency in the absence of any P3 capping group. The synthesis and preliminary SAR are described. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmcl.2013.12.060

文献信息

• Conversion of heavy petroleum oils
  申请人：MOBIL OIL CORPORATION

  公开号：EP0062720B1

  公开（公告）日：1985-04-17
• MELANGE D'ALKYL-ARYL-SULFONATES DE METAUX ALCALINO-TERREUX, SON APPLICATION COMME ADDITIF POUR HUILE LUBRIFIANTE ET PROCEDES DE PREPARATION
  申请人：Chevron Oronite S.A.

  公开号：EP0882116B1

  公开（公告）日：2001-12-05
• Copolymer containing functional group of sulfonic acid or its salt, and process for producing said copolymer
  申请人：Ihata Osamu

  公开号：US20070232767A1

  公开（公告）日：2007-10-04

  A copolymer comprising (i) an olefin unit selected from the group consisting of an ethylene unit and an α-olefin unit having 3 to 20 carbon atoms, and (ii) a unit of a compound represented by the formula, CH 2 ═CH—(R 1 ) m —SO 3 X; and a process for producing said copolymer comprising the step of contacting (i) the above-mentioned olefin, and (ii) the above-mentioned compound with a polymerization catalyst, wherein m is a number of 0 or 1, R 1 is an aliphatic hydrocarbylene group having 1 to 18 carbon atoms, and X is a mono-valent cationic species.
• US7816474B2
  申请人：——

  公开号：US7816474B2

  公开（公告）日：2010-10-19
• [EN] MIXTURE OF EARTH-ALKALINE METAL ALKYL-ARYL-SULPHONATES, ITS USE AS ADDITIVE FOR LUBRICATING OIL AND METHOD OF PREPARATION<br/>[FR] MELANGE D'ALKYL-ARYL-SULFONATES DE METAUX ALCALINO-TERREUX, SON APPLICATION COMME ADDITIF POUR HUILE LUBRIFIANTE ET PROCEDES DE PREPARATION
  申请人：CHEVRON CHEMICAL S.A.

  公开号：WO1998010044A1

  公开（公告）日：1998-03-12

  (EN) The invention concerns a mixture of superalkalified earth-alkaline comprising: (a) 50 % to 85 % by weight of one mono-alkyl-sulphonate with a C14-C40 linear chain in which the molar ratio of phenyl-sulphonate substituent in position 1 or 2 is between 0 and 13 %, and (b) 15 % to 50 % by weight of one heavy alkyl-aryl-sulphonate, in which the aryl radical is phenyl substituted or not and the alkyl chains are either two linear alkyl chains with a total of 16 to 40 carbon atoms or one or several branched alkyl chains with an average total of 15 to 48 carbon atoms. Insofar as these mixtures contain less than 10 % of linear mono-alkyl-phenyl-sulphonate substituted in position 1 or 2 of the linear alkyl chain, they have properties enabling their use as washing-dispering additive for lubricating oils.(FR) Un mélange d'alkyl-aryl-sulfonates alcalino-terreux suralcalinisés comportant: (a) 50 % à 85 % en poids d'un mono-alkyl-phényl-sulfonate à chaîne linéaire en C14-C40 dans lequel la proportion molaire de substituant phényl-sulfonate en position 1 ou 2 est comprise entre 0 et 13 %, et (b) 15 % à 50 % en poids d'un alkyl-aryl-sulfonate lourd, dans lequel le radical aryl est phényl ou non et les chaînes alkyl sont soit deux chaînes alkyles linéaires avec un total d'atomes de carbone de 16 à 40, soit une ou plusieurs chaînes alkyles ramifiées avec en moyenne un total d'atomes de carbone de 15 à 48. Dans la mesure où ces mélanges contiennent moins de 10 % de mono-alkyl-phényl-sulfonate linéaire substitué en position 1 ou 2 de la chaîne alkyle linéaire, ils présentent des propriétés les rendant aptes à leur utilisation comme additif détergent-dispersant pour huiles lubrifiantes.