tris(2-phenyl-1-aziridinyl)phosphine oxide | 5774-45-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: tris(2-phenyl-1-aziridinyl)phosphine oxide
• 英文别名: 1-Bis(2-phenylaziridin-1-yl)phosphoryl-2-phenylaziridine
• CAS: 5774-45-8；113084-44-9
• 化学式: C₂₄H₂₄N₃OP
• 分子量: 401.448
• InChiKey: YFJWWDRRRXFDTH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  26.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-苯基氮丙啶 在 三乙胺 、 三氯氧磷 作用下， 以 甲苯 为溶剂， 反应 38.0h， 以14%的产率得到tris(2-phenyl-1-aziridinyl)phosphine oxide
  参考文献：
  名称：

  Synthesis, molecular symmetry, and chemical reactivity of C-aryl-substituted phosphoraziridines

  摘要：

  DOI：

  10.1021/jo00243a030

文献信息

• TERMINAL-MODIFIED BLOCK COPOLYMER AND COMPOSITION CONTAINING SAID COPOLYMER
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0245505A1

  公开（公告）日：1987-11-19

  A terminal-modified block copolymer wherein an amino group- or amino group-containing, terminal-treating agent is bound to the terminals of the polymer. It is obtained by reacting the active terminals of a block copolymer of a conjugated diene with a vinylaromatic hydrocarbon comprising 5 to 95 % of a vinylaromatic hydrocarbon and having a number- average molecular weight of 5,000 to 1,000,000 (obtained by using at least one member selected from among alkali metals and organic alkali metal compounds as a polymerization initiator) with at least one terminal-treating agent selected from among imide compounds, cyanamide compounds, aziridinyl compounds, amide compounds, and other tertiary amino group-containing compounds. A pressure-sensitive adhesive composition excellent in adhesiveness and anti-creeping properties comprising said block copolymer and a tackifying resin, a water-absorbing composition comprising said block copolymer and a highly water-absorbing resin, a thermoplastic resin composition comprising said block copolymer and a thermoplastic resin, and a conductive composition comprising said block copolymer and a conductive material are also disclosed.

  一种末端改性嵌段共聚物，其中一种含氨基或氨基基团的末端处理剂与聚合物的末端结合。它是通过将共轭二烯与乙烯基芳烃的嵌段共聚物的活性末端与至少一种末端处理剂反应而得到的，该末端处理剂选自亚胺化合物、氰胺化合物、氮杂环丁基化合物、酰胺化合物和其他含三级氨基基团的化合物，乙烯基芳烃的含量为 5%至 95%，平均分子量为 5,000 至 1,000,000 （通过使用至少一种选自碱金属和有机碱金属化合物的成员作为聚合引发剂而得到）。此外，还公开了由所述嵌段共聚物和增粘树脂组成的粘合性和防蠕变性能优异的压敏胶组合物、由所述嵌段共聚物和高吸水性树脂组成的吸水组合物、由所述嵌段共聚物和热塑性树脂组成的热塑性树脂组合物以及由所述嵌段共聚物和导电材料组成的导电组合物。
• Compositions containing a terminal-modified block copolymer
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0473206A2

  公开（公告）日：1992-03-04

  An adhesive composition excellent in tackiness, adhesiveness, and creep resistance characteristic which comprises said block copolymer and a tackifier resin, a water-absorbing composition comprising said block copolymer and a highly water-absorbing resin, a thermoplastic resin composition comprising said block copolymer and a thermoplastic resin, and an electroconductive composition comprising said block copolymer and an electroconductive material, which consists of a terminal-modified block copolymer having the rest of the terminal-treating agent bonded to the polymer terminal which is obtained by treating the active terminal of a block copolymer comprising conjugated dienes and vinylaromatic hydrocarbon compounds which is obtained by using as the polymerization initiator at least one member selected from alkali metals or organoalkali metals and has a vinylaromatic hydrocarbon content of 5 to 95% by weight and a number average molecular weight of 5,000 to 1,000,000.

  一种粘合剂组合物，具有优异的粘性、粘附性和抗蠕变性，由所述嵌段共聚物和增粘树脂、由所述嵌段共聚物和高吸水性树脂组成的吸水组合物、由所述嵌段共聚物和热塑性树脂组成的热塑性树脂组合物以及由所述嵌段共聚物和导电材料组成的导电组合物构成、其中包括一种末端改性嵌段共聚物，其末端处理剂的其余部分与聚合物末端结合，该聚合物末端是通过处理由共轭二烯和乙烯基芳烃化合物组成的嵌段共聚物的活性末端而获得的，该嵌段共聚物是通过使用至少一种选自碱金属或有机碱金属的成员作为聚合引发剂而获得的，其乙烯基芳烃含量为 5%至 95%（按重量计），平均分子量为 5,000 至 1,000,000 。
• POLYVINYL ALCOHOL RESIN COMPOSITION AND MULTILAYER PACKAGES
  申请人：Kuraray Co., Ltd.

  公开号：EP1316582A1

  公开（公告）日：2003-06-04

  The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises 70 to 99.9 wt% of a polyvinyl alcohol resin (A) and 0.1 to 30 wt% of a thermoplastic resin (B) other than the polyvinyl alcohol resin (A), wherein the thermoplastic resin (B) has a carbon-carbon double bond and a functional group including a hetero atom, and an oxygen absorption rate of the resin composition is 0.001 ml/m2 • day or more.

  本发明提供了一种具有氧清除功能的树脂组合物。该树脂组合物包括 70 至 99.9 wt%的聚乙烯醇树脂（A）和 0.1 至 30 wt%的除聚乙烯醇树脂（A）之外的热塑性树脂（B），其中热塑性树脂（B）具有碳碳双键和包括杂原子的官能团，该树脂组合物的吸氧率为 0.001 ml/m2 - 天或以上。
• Polyvinyl alcohol resin composition and multilayer packages
  申请人：——

  公开号：US20030022974A1

  公开（公告）日：2003-01-30

  The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises 70 to 99.9 wt % of a polyvinyl alcohol resin (A) and 0.1 to 30 wt % of a thermoplastic resin (B) other than the polyvinyl alcohol resin (A), wherein the thermoplastic resin (B) has a carbon-carbon double bond and a functional group including a hetero atom, and an oxygen absorption rate of the resin composition is 0.001 m//m 2 day or more.

  本发明提供了一种具有氧清除功能的树脂组合物。该树脂组合物包括 70 至 99.9 wt % 的聚乙烯醇树脂（A）和 0.1 至 30 wt % 的除聚乙烯醇树脂（A）之外的热塑性树脂（B），其中热塑性树脂（B）具有碳碳双键和包括杂原子的官能团，该树脂组合物的吸氧率为 0.001 m//m 2 天或以上。
• PERLMAN, MICHAEL E.;BARDOS, THOMAS J., J. ORG. CHEM., 53,(1988) N 8, 1761-1767
  作者：PERLMAN, MICHAEL E.、BARDOS, THOMAS J.

  DOI：——

  日期：——