n-propyl 2-benzylacrylate | 1619998-78-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: n-propyl 2-benzylacrylate
• 英文别名: Propyl 2-benzylprop-2-enoate
• CAS: 1619998-78-5
• 化学式: C₁₃H₁₆O₂
• 分子量: 204.269
• InChiKey: KLAZUTUUWCBNFJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  苯甲醛 在 二氢吡啶 、 L-脯氨酸 作用下， 以 甲醇 为溶剂， 反应 14.0h， 生成 n-propyl 2-benzylacrylate
  参考文献：
  名称：

  高产的手性和非手性α-取代的丙烯酸酯的顺序一锅合成通过无金属还原偶合反应†

  摘要：

  通过无金属还原偶联反应的顺序一锅法结合然后进行Eschenmoser甲基化，可以实现高产率合成取代的手性和非手性α-取代的丙烯酸酯的一般方法。在醇溶剂存在下，Eschenmoser盐能成功地使脯氨酸催化Meldrum的酸，醛和Hantzsch酯的甲基化反应。本文中，我们显示了由手性/非手性α-取代丙烯酸酯高特权合成的合成原料，并显示它们是药物和天然产物合成中非常好的中间体。

  DOI：

  10.1039/c4ob00667d

文献信息

• Method of forming gaskets by injection and compositions for use therein
  申请人：LOCTITE (IRELAND) Ltd.

  公开号：EP0408317A2

  公开（公告）日：1991-01-16

  A method of forming a gasket in situ between two components which comprises injecting into a groove in at least one of said components a curable composition comprising: one or more free-radical polymerizable vinyl esters, and ingredients of a rapid free-radical cure system therefor, the cure system being inactivated prior to injection of the composition, and the composition having a viscosity at 25oC in the range from 200 to 500,000 mPas; and permitting the composition to cure. The composition can be a two part composition wherein the first part contains a prepolymer, monomer and activator and the second part a prepolymer, monomer and activator. The composition can also comprise two expansion reactants, each in a separate part of the composition prior to injection, which react to form a gas in situ in the composition. The gasketing composition is suitable for use in engines and other machines e.g. in industrial manufacturing plants.

  一种在两个部件之间就地形成垫圈的方法，包括将一种可固化组合物注入至少一个部件的凹槽中，该组合物包括 一种或多种可自由基聚合的乙烯基酯，及其快速自由基固化体系的成分，固化体系在注入组合物之前失活、 该组合物在 25oC 时的粘度范围为 200 至 500,000 mPas； 允许组合物固化。 该组合物可以是两部分组合物，其中第一部分包含预聚物、单体和活化剂，第二部分包含预聚物、单体和活化剂。该组合物还可以包含两种膨胀反应物，在注入之前，每种反应物都在组合物的一个单独部分中，它们在组合物中发生反应，就地形成气体。这种密封组合物适用于发动机和其他机器，例如工业制造工厂。
• Modified rubber compositions for reinforcing polyacrylate products
  申请人：RÖHM GMBH

  公开号：EP0451310A1

  公开（公告）日：1991-10-16

  Modified rubber compositions comprise by weight about 15-60% of a highly saturated aliphatic rubber such as ethylene-propylene-diene rubber, about 25-80% of acrylate monomer units; and less than about out 5% multi-functional monomer units. The compositions exist as amorphous heterogeneously dispersed phases. The first phase comprises the copolymer rubber to which polymers of at least 10%, preferably 20%, and more preferably 30% of the other monomer units are grafted. The second phase comprises the other monomers polymerized as homo and copolymers, not grafted to the rubber. Optionally, up to 20% of the composition comprises high index monomer units, e.g., those providing phenyl groups (preferably styrene) having an index of refraction greater than that off the rubber, preferably greater than that of polyacrylate. The high index monomer units may be copolymerized with the acrylate and grafted to the rubber. Greater than 10% and preferably 20% of the monomer units other than rubber are grafted to the rubber. The number average molecular weight of the grafts is between 10,000 and 80,000 daltons. bout 2-20% by weight of one or more polymers may be provided to adjust the refractive indices of the rubber or the polyacrylate phase in the final product such that when the composition is present at the 10% rubber level, the haze can be reduced to less than 20%., Examples for modifying the refractive index of the rubber phase, other than those grafted to the rubber, are block copolymers comprising at least one block providing high index monomer units (preferably styrene) having a higher refractive index than rubber, preferably higher than polyacrylate and at least one block of a saturated aliphatic polymer compatible with the rubber, such as hydrogenated polyisoprene., Other polymers compatible with the polyacrylate phase and having a lower index of refraction than that of polyacrylate, preferably less than the rubber such as those providing vinylidene fluoride monomer units may be utilized. The compositions may be stored and transported to the place of manufacture of polyacrylate products and there incorporated into polyacrylate products to form up to about 80% by weight of said products having high strength and if desired, high clarity.

  改性橡胶组合物按重量计包括约 15-60%的高饱和脂肪族橡胶（如乙烯-丙烯-二烯橡胶）、约 25-80%的丙烯酸酯单体单元和小于约 5%的多功能单体单元。组合物以无定形异质分散相的形式存在。第一相由共聚橡胶组成，共聚橡胶上接枝了至少 10% 的聚合物，最好是 20%，更多的是 30% 的其他单体单元。第二相包括未接枝到橡胶上的其他单体聚合为均聚物和共聚物。可选地，组合物中最多 20% 的单体单元为高折射率单体单元，例如，提供苯基（最好是苯乙烯）的单体单元，其折射率大于橡胶的折射率，最好大于聚丙烯酸酯的折射率。高折射率单体单元可与丙烯酸酯共聚并接枝到橡胶上。橡胶以外的单体单元接枝到橡胶上的比例大于 10%，最好是 20%。接枝物的平均分子量介于 10,000 和 80,000 道尔顿之间。 可提供约 2-20% （按重量计）的一种或多种聚合物，以调整最终产品中橡胶或聚丙烯酸酯相的折射率，从而当组合物中橡胶含量为 10% 时，雾度可降至 20% 以下。除了接枝到橡胶上的聚合物外，还可以使用嵌段共聚物来改变橡胶相的折射率，嵌段共聚物包括至少一个提供高折射率单体单元（最好是苯乙烯）的嵌段，其折射率高于橡胶，最好高于聚丙烯酸酯，以及至少一个与橡胶相容的饱和脂肪族聚合物嵌段，如氢化聚异戊二烯、也可使用与聚丙烯酸酯相容且折射率低于聚丙烯酸酯（最好低于橡胶）的其他聚合物，如提供偏氟乙烯单体单元的聚合物。这些组合物可以储存和运输到聚丙烯酸酯产品的制造地，并在那里掺入聚丙烯酸酯产品中，形成重量比高达约 80% 的具有高强度和高透明度（如果需要）的上述产品。
• Anaerobically-curable flexible sealant compositions
  申请人：LOCTITE (IRELAND) LIMITED

  公开号：EP0640672A1

  公开（公告）日：1995-03-01

  One-part anaerobically curable compositions for producing flexible flange sealants comprising in combination: (A) a flexible urethane type (meth)acrylate prepolymer having a urethane structure in the main chain thereof and having (meth)acrylate end groups, the average molecular weight of the prepolymer (A) being more than 3,000 and less than 10,000, (B) a urethane type (meth)acrylate prepolymer having a urethane structure in the main chain thereof and having (meth)acrylate end groups, the average molecular weight of the prepolymer (B) being the range 1,000 - 3,000, (C) one or more phenyl substituted mono (meth)acrylate monomers which are miscible with or soluble in the prepolymers (A) and (B).

  用于生产柔性法兰密封胶的单组分厌氧固化组合物，其组合物包括 (A) 在主链中具有氨基甲酸酯结构并具有(甲基)丙烯酸酯端基的柔性氨基甲酸酯型 (甲基)丙烯酸酯预聚物，预聚物(A)的平均分子量大于 3,000 且小于 10,000、 (B) 聚氨酯型(甲基)丙烯酸酯预聚物，其主链具有聚氨酯结构，并具有(甲基) 丙烯酸酯端基，预聚物(B)的平均分子量在 1,000-3,000 之间、 (C) 一种或多种苯基取代的单（甲基）丙烯酸酯单体，可与预聚物 (A) 和 (B) 混溶或溶于预聚物 (A) 和 (B)。
• Inkjet ink composition
  申请人：Hewlett-Packard Development Company, L.P.

  公开号：US10738208B2

  公开（公告）日：2020-08-11

  The present disclosure refers to an inkjet ink composition comprising an ink vehicle including water; a white metal oxide pigment dispersed in the ink vehicle; and a latex binder, dispersed in the ink vehicle. The latex binder includes a first heteropolymer including two or more aliphatic (meth)acrylate ester monomers or two or more aliphatic (meth)acrylamide monomers; and a second heteropolymer including a cycloaliphatic monomer and an aromatic monomer. The present disclosure refers also to a printing method using such inkjet ink composition.

  本公开涉及一种喷墨墨水组合物，包括一种墨水载体，其中包括水；一种分散在墨水载体中的白色金属氧化物颜料；以及一种分散在墨水载体中的胶乳粘合剂。胶乳粘合剂包括第一杂聚合物，包括两种或两种以上脂肪族（甲基）丙烯酸酯单体或两种或两种以上脂肪族（甲基）丙烯酰胺单体；以及第二杂聚合物，包括环脂族单体和芳香族单体。本公开还涉及使用这种喷墨墨水组合物的印刷方法。
• Inkjet ink set
  申请人：Hewlett-Packard Development Company, L.P.

  公开号：US10883008B2

  公开（公告）日：2021-01-05

  The present disclosure refers to an inkjet ink set comprising a black ink with a black pigment, a yellow ink with a yellow pigment, a cyan ink with a cyan pigment, a magenta ink with a magenta pigment and a white ink with a white pigment. At least one of the ink further contains a latex binder that is dispersed in the ink vehicle, and that includes a first heteropolymer including two or more aliphatic (meth)acrylate ester monomers or two or more aliphatic (meth)acrylamide monomers; and a second heteropolymer including a cycloaliphatic monomer and an aromatic monomer. The present disclosure refers also to a printing method using the ink set and to a system for printing the ink set.

  本公开涉及一种喷墨墨水组合，包括含有黑色颜料的黑色墨水、含有黄色颜料的黄色墨水、含有青色颜料的青色墨水、含有品红色颜料的品红色墨水和含有白色颜料的白色墨水。其中至少一种油墨还含有分散在油墨载体中的乳胶粘合剂，该粘合剂包括第一杂聚合物，包括两种或两种以上脂肪族（甲基）丙烯酸酯单体或两种或两种以上脂肪族（甲基）丙烯酰胺单体；以及第二杂聚合物，包括环脂族单体和芳香族单体。本公开还涉及使用该油墨组的印刷方法和印刷该油墨组的系统。