tetrakis-[(6,7,8,8a-tetrahydro-4aH-[1,4]dithiino-[2,3-b]pyrano)]porphyrazin | 642459-66-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: tetrakis-[(6,7,8,8a-tetrahydro-4aH-[1,4]dithiino-[2,3-b]pyrano)]porphyrazin
• CAS: 642459-66-3
• 化学式: C₃₆H₃₄N₈O₄S₈
• 分子量: 899.245
• InChiKey: ZHSNHXLROHOAOB-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  tetrakis-[(6,7,8,8a-tetrahydro-4aH-[1,4]dithiino-[2,3-b]pyrano)]porphyrazin 、 zinc(II) acetylacetonate 以 四氢呋喃 为溶剂， 以46.72%的产率得到tetrakis-[(6,7,8,8a-tetrahydro-4aH-[1,4]dithiino-[2,3-b]pyrano)]porphyrazinato zinc(II)
  参考文献：
  名称：

  Synthesis and electrochemical properties of porphyrazines with annulated 1,4-dithiaheterocycles

  摘要：

  Porphyrazines (M=H, Mg, Zn or Cu) with 2,3-trimethyleneoxy-2,3-dihydro-1,4-dithiin or 2-ethoxy-2,3-dihydro-1,4-dithiin groups fused to each pyrrol unit have been synthesised starting with the corresponding unsaturated dicarbonitrile derivative. The elemental analysis and IR, H-1 NMR, UV-Vis and mass spectral data have been used to characterise the new compounds. Electrochemical investigations have shown that metal insertion into the porphyrazine core and substituents having high electron donating ability shift the ring centred reduction processes towards negative potentials. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00463-7