[μ-p-benzoquinone-2,5-bis(anilino)]bis[(triphenylphosphane)phenylnickel(II)] | 561068-03-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [μ-p-benzoquinone-2,5-bis(anilino)]bis[(triphenylphosphane)phenylnickel(II)]
• CAS: 561068-03-9
• 化学式: C₆₆H₅₂N₂Ni₂O₂P₂
• 分子量: 1084.48
• InChiKey: HUXHUCDHYTWKEW-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  trans-chloro(phenyl)bis(triphenylphosphine)nickel(II) 、 2,5-bis(anilino)-p-benzoquinone lithium salt 以 甲苯 为溶剂， 以72.3%的产率得到[μ-p-benzoquinone-2,5-bis(anilino)]bis[(triphenylphosphane)phenylnickel(II)]
  参考文献：
  名称：

  Novel, Highly Active Binuclear 2,5-Disubstituted Amino-p-benzoquinone−Nickel(II) Ethylene Polymerization Catalysts

  摘要：

  Reaction of salts of the 2,5-disubstituted amino-p-benzoquinone bridging ligand (la-e) with trans-bis(triphenylphosphane)phenylnickel(II) chloride results in the binuclear complexes 2a-e, which show high activities for ethylene polymerization without any cocatalysts. High-molecular-weight, moderately branched polyethylene of broad molecular-weight distribution was obtained.

  DOI：

  10.1021/om030068y