triiodo(tetrahydrofuran-O)antimony(III) | 193958-38-2

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: triiodo(tetrahydrofuran-O)antimony(III)
• 英文别名: antimony(3+);oxolane;triiodide
• CAS: 193958-38-2
• 化学式: C₄H₈I₃OSb
• 分子量: 574.57
• InChiKey: MWFQCUNAEKBOSR-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -8.57
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 碘化锑 在 tetracyanoethene 作用下， 以 四氢呋喃 为溶剂， 生成 triiodo(tetrahydrofuran-O)antimony(III)
  参考文献：
  名称：

  Tetrahydrofuran Adducts of a Chlorobismuthate(III) Anion and Antimony Triiodide

  摘要：

  Tetrahydrofuran (thf) adducts of a chlorobismuthate(III) and of antimony triiodide have been pre and characterized by X-ray crystallography. The former compound, bis[tetrakis(tetrahydrofuran-O)-lithium(I)] di-mu-chloro-bis[trichloro(tetrahydrofuran-O)-bismuthate(III)], [Li(C4H8O)(4)](2)[Bi2Cl8(C4H8O)(2)], contains centrosymmetric edge-shared bi-octahedral dianions with the formula [Bi2Cl6(thf)(2)(mu-Cl)(2)](2-) in which the thf ligands occupy terminal sites at 90 degrees to the Bi-2(mu-Cl)(2) plane; the cations are [Li(thf)(4)](+). The latter structure, triiodo(tetrahydrofuran-O)antimony(III), [SbI3(C4H8O)], comprises a polymeric arrangement of SbI3(thf) units, the antimony centres being bridged alternately by pairs of I atoms and pairs of thf ligands.

  DOI：

  10.1107/s0108270197004009