| 1574363-21-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• CAS: 1574363-21-5
• 化学式: C₁₅H₂₁NO₂
• 分子量: 247.337
• InChiKey: NXDHVGDVEMMANI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.88
• 重原子数：
  18.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  29.54
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) 、 在 copper(l) chloride 作用下， 以 二氯甲烷 为溶剂， 反应 0.67h， 以65.7%的产率得到C₃₄H₄₃Cl₂N₃O₂Ru
  参考文献：
  名称：

  Synthesis, structure and catalytic study of oxygen chelated ruthenium (II) carbene complex

  摘要：

  New oxygen chelated ruthenium carbene complex containing carbonyl oxygen and ether oxygen has been developed. The X-ray structure of the complex showed that the carbonyl oxygen of the amide and the terminal oxygen of the benzylidene ether are both coordinated to the metal to give an octahedral structure. The catalytic activities of this new complex for olefin metathesis reactions were investigated and it exhibited excellent performances for the ring-closing metathesis (RCM) of diethyl diallymalonate at 30 degrees C and even at 0 degrees C. The initiation rate of the catalyst was higher than that for the Hoveyda catalyst ((H(2)IMes)(Cl)(2)Ru = C(H)(C6H4-2-OiPr)) and it was also active for cross metathesis (CM). (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2014.03.034
• 作为产物：
  描述：

  4-methyl-2-(prop-1-enyl)phenol 在 氯化亚砜 、 potassium carbonate 、 sodium hydroxide 作用下， 以 丙酮 、 苯 为溶剂， 反应 22.0h， 生成
  参考文献：
  名称：

  Synthesis, structure and catalytic study of oxygen chelated ruthenium (II) carbene complex

  摘要：

  New oxygen chelated ruthenium carbene complex containing carbonyl oxygen and ether oxygen has been developed. The X-ray structure of the complex showed that the carbonyl oxygen of the amide and the terminal oxygen of the benzylidene ether are both coordinated to the metal to give an octahedral structure. The catalytic activities of this new complex for olefin metathesis reactions were investigated and it exhibited excellent performances for the ring-closing metathesis (RCM) of diethyl diallymalonate at 30 degrees C and even at 0 degrees C. The initiation rate of the catalyst was higher than that for the Hoveyda catalyst ((H(2)IMes)(Cl)(2)Ru = C(H)(C6H4-2-OiPr)) and it was also active for cross metathesis (CM). (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2014.03.034