3-(methoxymethyl)-1-methylimidazolium fluoride | 1099615-13-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 3-(methoxymethyl)-1-methylimidazolium fluoride
• 英文别名: 1-(Methoxymethyl)-3-methylimidazol-3-ium;fluoride
• CAS: 1099615-13-0
• 化学式: C₆H₁₁N₂O*F
• 分子量: 146.165
• InChiKey: OQDOWBCVIVHDBZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -3.08
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  18
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Ionic liquids as solvents
  申请人：Pagoria Philip F.

  公开号：US20090012297A1

  公开（公告）日：2009-01-08

  A method in one embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having a fluoride anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of about 90° C. or less during the contacting. A method in another embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having an acetate or formate anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of less than about 90° C. during the contacting. A method for purifying a strongly hydrogen bonded organic material according to one another embodiment includes dissolving a strongly hydrogen bonded organic material, selected from a group consisting of 1,3,5-triamino-2,4,6-trinitrobenzene and 2,6-diamino-3,5-dinitropyrazine-1-oxide, in a solution comprising an ionic liquid, the ionic liquid having an anion selected from a group consisting of a fluoride anion, an acetate anion, and a formate anion; maintaining the solution at a temperature of about 70° C. or less during the contacting; and recrystallizing the strongly hydrogen bonded organic material.

  一种实施例的方法包括将强氢键有机材料与具有氟化物阴离子的离子液体接触以使强氢键有机材料溶解；并在接触期间将离子液体保持在约90°C或更低的温度。另一实施例的方法包括将强氢键有机材料与具有醋酸盐或甲酸盐阴离子的离子液体接触以使强氢键有机材料溶解；并在接触期间将离子液体保持在约90°C以下的温度。根据另一实施例的强氢键有机材料纯化方法包括将强氢键有机材料（从由1,3,5-三氨基-2,4,6-三硝基苯和2,6-二氨基-3,5-二硝基吡嗪-1-氧化物组成的组中选择）溶解在包括离子液体的溶液中，所述离子液体具有从氟化物阴离子、醋酸盐阴离子和甲酸盐阴离子组成的阴离子；在接触期间将溶液保持在约70°C或更低的温度；并重新结晶强氢键有机材料。
• US8071813B2
  申请人：——

  公开号：US8071813B2

  公开（公告）日：2011-12-06