2-(bis-dibutylcarbamoylmethyl-amino)-N,N-dibutyl-acetamide | 69519-28-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-(bis-dibutylcarbamoylmethyl-amino)-N,N-dibutyl-acetamide
• 英文别名: 2-(bis(dibutylcarbamoylmethyl)amino)-N,N-dibutylacetamide；2-[bis[2-(dibutylamino)-2-oxoethyl]amino]-N,N-dibutylacetamide
• CAS: 69519-28-4
• 化学式: C₃₀H₆₀N₄O₃
• 分子量: 524.831
• InChiKey: GAEBQPMHFZUJBW-UHFFFAOYSA-N

物化性质

• 沸点：
  628.0±50.0 °C(Predicted)
• 密度：
  0.964±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.57
• 重原子数：
  37.0
• 可旋转键数：
  24.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  64.17
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  terbium(III) picrate 、 2-(bis-dibutylcarbamoylmethyl-amino)-N,N-dibutyl-acetamide 以 乙醇 为溶剂， 生成 [Tb(picrate)3(2-bis(dibutylcarbamoylmethyl)amino)-N,N-dibutylacetamide)]
  参考文献：
  名称：

  Synthesis, characterization of 2-(bis-dibutylcarbamoylmethyl-amino)-N, N-dibutyl-acetamide (L) lanthanide picrate complexes (Ln=Nd, Eu, Tb) and the crystal structure of [Tb(pic)3L]

  摘要：

  Solid complexes of lanthanide picrate with the ligand 2-(bis-dibutylcarbamoylmethyl-amino)-N, N-dibutyl-acetamide (L), [Ln(PiC)(3)L] (Ln = Nd, Eu, Th), have been prepared and characterized by elemental analysis, conductivity measurements, DTA and TGA analysis, IR and H-1 NMR spectra. For the terbium complex, X-ray measurements show that Tb(III) ion is 9-coordinated by three oxygen atoms and one nitrogen atom of L and five oxygen atoms of picrate groups. Molecule B has a clockwise structure due to the screw coordination arrangement of the tripod-type ligand. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(03)00368-5
• 作为产物：
  描述：

  次氮基三乙酸 在 草酰氯 、 N,N-二甲基甲酰胺 作用下， 以 苯 为溶剂， 反应 14.0h， 生成 2-(bis-dibutylcarbamoylmethyl-amino)-N,N-dibutyl-acetamide
  参考文献：
  名称：

  Synthesis, characterization of 2-(bis-dibutylcarbamoylmethyl-amino)-N, N-dibutyl-acetamide (L) lanthanide picrate complexes (Ln=Nd, Eu, Tb) and the crystal structure of [Tb(pic)3L]

  摘要：

  Solid complexes of lanthanide picrate with the ligand 2-(bis-dibutylcarbamoylmethyl-amino)-N, N-dibutyl-acetamide (L), [Ln(PiC)(3)L] (Ln = Nd, Eu, Th), have been prepared and characterized by elemental analysis, conductivity measurements, DTA and TGA analysis, IR and H-1 NMR spectra. For the terbium complex, X-ray measurements show that Tb(III) ion is 9-coordinated by three oxygen atoms and one nitrogen atom of L and five oxygen atoms of picrate groups. Molecule B has a clockwise structure due to the screw coordination arrangement of the tripod-type ligand. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(03)00368-5

文献信息

• Self-organization of chiral self-complementary europium complex with a new achiral tripod-type ligand: Synthesis and stereochemistry effects to complex luminescence properties
  作者：Jiangrong Zheng、Nan Yang、Weisheng Liu、Kaibei Yu

  DOI：10.1016/j.molstruc.2007.03.008

  日期：2008.2

  Solid complexes of europium picrate with the ligands: 2-(bis-dibutylcarbamoylmethyl-amino)-N,N-dibutyl-acetamid (L-1), 2-bis-[(ethyl-phenyl-carbamoyl)-methyl]-amino}-N-ethyl-N-phenyl-acetamide (L-2) and 2-(bis-diethylcarbamoyl methyl-amino)-N,N-diethylacetamide (L-3) were prepared and characterized by elemental analysis, conductivity measurements and IR spectra. For the [Eu(pic)(3)L-1], X-ray measurements show that the screw coordination arrangement of the achiral tripod-type ligand (L-1) around the Eu(III) ion induces the chirality of clockwise (C) and anticlockwise (A) molecular structures. And, the luminescence properties of tripod-type ligands with Eu(III) ion were affected by the complex stereochemistry. (c) 2007 Elsevier B.V. All rights reserved.