3,6-diiodo-9-propylcarbazole | 1391973-54-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,6-diiodo-9-propylcarbazole
• 英文别名: 3,6-diiodo-9-propyl-9H-carbazole
• CAS: 1391973-54-8
• 化学式: C₁₅H₁₃I₂N
• 分子量: 461.084
• InChiKey: ZLTBCNOQBISFMK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3,6-diiodo-9-propylcarbazole 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 tetrakis(actonitrile)copper(I) hexafluorophosphate 、 tris[(1-benzyl-1H-1,2,3-triazol-4-yl)methyl]amine 、 三乙胺 、 N,N-二异丙基乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 144.0h， 生成
  参考文献：
  名称：

  卤素键联双三唑烷轮烷用于卤化物选择性阴离子的识别

  摘要：

  对无环卤素和氢键合的双三唑鎓咔唑受体的阴离子结合性质进行了系统的研究。发现与卤素键合的双碘三唑鎓咔唑受体的卤化物结合效能远远优于其与氢键合的双三唑鎓类似物。这导致了含有双碘三唑鎓咔唑轴组分的卤素键和氢键混合轮烷的主体的合成。通过在竞争性水性溶剂混合物中进行1 H NMR滴定实验确定的轮烷的阴离子识别特性表明，预组织的卤素键联锁主体腔具有卤化物选择性，对溴化物具有很强的结合亲和力。

  DOI：

  10.1002/chem.201405578
• 作为产物：
  描述：

  咔唑 在 N-碘代丁二酰亚胺 、 四丁基碘化铵 、 溶剂黄146 、 sodium hydroxide 作用下， 以 氯仿 、 水 、 甲苯 为溶剂， 反应 8.0h， 生成 3,6-diiodo-9-propylcarbazole
  参考文献：
  名称：

  全卤素键轮烷对水介质中卤化物的选择性传感

  摘要：

  描述了第一轮烷烃主体系统的合成和阴离子结合特性，该系统仅通过卤素键结合并感测阴离子。通过极化碘代三唑和碘代三唑鎓卤素键供体的组合，可形成三维腔，用于阴离子结合。该轮烷在大环组分内结合了发光的（（I）联吡啶金属传感器基序，从而能够对阴离子结合特性进行光学研究。轮烷的拓扑结构已通过单晶X射线结构分析得到证实，表明亲电子碘原子与氯离子之间存在卤素键。在50％H 2 O / CH 3中CN溶剂混合物中，轮烷烷主体在一定范围的含氧阴离子上对氯离子，溴离子和碘离子具有很强的结合亲和力和选择性。

  DOI：

  10.1002/anie.201403659

文献信息

• Solvent‐Dependent Nanostructures Based on Active π‐Aggregation Induced Emission Enhancement of New Carbazole Derivatives of Triphenylacrylonitrile
  作者：Santu Maity、Krishnendu Aich、Chandraday Prodhan、Keya Chaudhuri、Ajoy Kumar Pramanik、Siddhartha Das、Jhuma Ganguly

  DOI：10.1002/chem.201900312

  日期：2019.3.27

  carbazole and 2,3,3‐triphenylacrylonitrile (TPAN) nanostructures (2‐CTPAN and 2,2′‐CTPAN) have been designed and synthesized by Pd‐catalyzed Sonogashira cross‐coupling reaction. CTPAN exhibit aggregation‐induced emission enhancement (AIEE) behavior in water with high fluorescence quantum yield. Both the compounds show tunable self‐assembly in water as well as in N,N‐dimethylformamide (DMF) by extended π–π

  在本研究中，咔唑和2,3,3-三苯基丙烯腈（TPAN）纳米结构（2-CTPAN和2,2'-CTPAN）是通过Pd催化的Sonogashira交叉偶联反应设计和合成的。CTPAN在具有高荧光量子产率的水中表现出聚集诱导的发射增强（AIEE）行为。通过扩展的π-π堆积相互作用，这两种化合物在水中以及在N，N-二甲基甲酰胺（DMF）中均显示出可调谐的自组装。CTPAN可以在水中自组装成球形颗粒，并且已经使用X射线衍射研究了这些自组装的结构。有趣的是，2-CTPAN和2,2'-CTPAN形成临界凝胶浓度（CGC）为11和15 mg mL -1的有机凝胶。在DMF中分别呈针状和棒状形态。2-CTPAN的单晶结构表明分子间CH-H⋅⋅⋅π相互作用将分子构象锁定为阶梯形超分子组装。这些AIEE活性化合物具有高水分散性，强黄色荧光和高量子产率，有前途的光稳定性和出色的生物相容性，使其成为潜在的生物成像剂。
• NOVEL TRIARYLAMINE POLYMER, PROCESS FOR PRODUCING THE SAME, AND USE THEREOF
  申请人：Tosoh Corporation

  公开号：EP1528074A1

  公开（公告）日：2005-05-04

  It is an object of the present invention to provide a novel triarylamine polymer which is excellent in solubility and film-forming property and has improved thermal stability; a simple process for its production; and an electronic element employing it. A triarylamine polymer represented by the following formula (1) (wherein each of Ar1, Ar2, Ar3, Ar4, Ar5, Ar6 and Ar7 which are independent of one another, is an unsubstituted or substituted C6-60 aromatic group, Ar1 and Ar2 are the same or different, Ar3 and Ar4 are the same or different, and m is an integer of at least 1), a process for its production, and an electronic element employing it, are provided:

  本发明的目的是提供一种新型三芳基胺聚合物，该聚合物具有优异的溶解性和成膜性，并具有更好的热稳定性；提供一种简单的生产工艺；以及提供一种使用该聚合物的电子元件。 本发明提供了由下式（1）代表的三芳基胺聚合物（其中，Ar1、Ar2、Ar3、Ar4、Ar5、Ar6 和 Ar7 中的每一个彼此独立，是未取代或取代的 C6-60 芳族基团，Ar1 和 Ar2 相同或不同，Ar3 和 Ar4 相同或不同，且 m 是至少 1 的整数）、其生产工艺以及使用该聚合物的电子元件：
• Novel triarylamine polymer, process for its production and its use
  申请人：TOSOH CORPORATION

  公开号：EP2327739A1

  公开（公告）日：2011-06-01

  It is an object of the present invention to provide a novel triarylamine polymer which is excellent in solubility and film-forming property and has improved thermal stability; a simple process for its production; and an electronic element employing it. A triarylamine polymer represented by the following formula (1) (wherein each of Ar1, Ar2, Ar3, Ar4, Ar5, Ar6 and Ar7 which are independent of one another, is an unsubstituted or substituted C6-60 aromatic group, Ar1 and Ar2 are the same or different, Ar3 and Ar4 are the same or different, and m is an integer of at least 1), a process for its production, and an electronic element employing it, are provided:

  本发明的目的是提供一种新型三芳基胺聚合物，该聚合物具有优异的溶解性和成膜性，并具有更好的热稳定性；提供一种简单的生产工艺；以及提供一种使用该聚合物的电子元件。 本发明提供了由下式（1）代表的三芳基胺聚合物（其中，Ar1、Ar2、Ar3、Ar4、Ar5、Ar6 和 Ar7 中的每一个彼此独立，是未取代或取代的 C6-60 芳族基团，Ar1 和 Ar2 相同或不同，Ar3 和 Ar4 相同或不同，且 m 是至少 1 的整数）、其生产工艺以及使用该聚合物的电子元件：
• Calix[4]arene–carbazole-containing polymers: Synthesis and properties
  作者：Patrícia D. Barata、Alexandra I. Costa、José V. Prata

  DOI：10.1016/j.reactfunctpolym.2012.06.006

  日期：2012.9

  New highly fluorescent calix[4]arene-containing phenylene-alt-ethynylene-3,6- and 2,7-carbazolylene polymers (CALIX-PPE-CBZs) have been synthesized for the first time and their photophysical properties evaluated. Both polymers were obtained in good isolated yields (70-84%), having M-w ranging from 7660-26,700 g mol(-1). It was found that the diethynyl substitution (3,6- or 2,7-) pattern on the carbazole monomers markedly influences the degree of polymerization. The amorphous yellow polymers are freely soluble in several nonprotic organic solvents and have excellent film forming abilities. TG/DSC analysis evidences similar thermal behaviors for both polymers despite their quite different molecular weight distributions and main-chain connectivities (T-g, in the range 83-95 degrees C and decomposition onsets around 270 degrees C).The different conjugation lengths attained by the two polymers dictates much of their photophysical properties. Thus, whereas the fully conjugated CAUX-PPE-2,7-CBZ has its emission maximum at 430 nm (E-g = 2.84 eV; Phi(F) = 0.62, CHCl3), the 3,6-linked counterpart (CALIX-PPE-3,6-CBZ) fluoresces at 403 nm with a significant lower quantum yield (E-g = 3.06 eV; Phi(F) = 0.31, CHCl3). The optical properties of both polymers are predominantly governed by the intrachain electronic properties of the conjugated backbones owing to the presence of calix[4]arenes along the polymer chain which disfavor significant interchain interactions, either in fluid- or solid-state. (C) 2012 Elsevier Ltd. All rights reserved.
• Novel triarylamine polymer, process for producing the same, and use thereof
  申请人：——

  公开号：US20040262574A1

  公开（公告）日：2004-12-30

  It is an object of the present invention to provide a novel triarylamine polymer which is excellent in solubility and film-forming property and has improved thermal stability; a simple process for its production; and an electronic element employing it. A triarylamine polymer represented by the following formula (1) (wherein each of Ar 1 , Ar 2 , Ar 3 , Ar 4 , Ar 5 , Ar 6 and Ar 7 which are independent of one another, is an unsubstituted or substituted C 6-60 aromatic group, Ar 1 and Ar 2 are the same or different, Ar 3 and Ar 4 are the same or different, and m is an integer of at least 1), a process for its production, and an electronic element employing it, are provided: 1