[Ge(BH3)(N(SiMe3)C(Ph)C(SiMe3)(pyridyl-2))H] | 889888-96-4

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Ge(BH3)(N(SiMe3)C(Ph)C(SiMe3)(pyridyl-2))H]
• CAS: 889888-96-4
• 化学式: C₁₉H₃₁BGeN₂Si₂
• 分子量: 427.041
• InChiKey: BBPDOETZESWDMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [{N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)}GeCl] 、 sodium tetrahydroborate 以 四氢呋喃 为溶剂， 以42%的产率得到[Ge(BH3)(N(SiMe3)C(Ph)C(SiMe3)(pyridyl-2))H]
  参考文献：
  名称：

  Reactivity of Pyridyl-1-azaallyl Germanium(II) Chloride:  Synthesis of Novel Lithium Germinate [{(PhC⋮C)₃Ge}₃GeLi(Et₂O)₃] and Ge(II)−M(I) (M = Cu and Au) Adducts

  摘要：

  The reaction of [Ge{N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)}Cl] (1) with LiBut or LiC equivalent to CPh in Et2O afforded substituted products [Ge(R){N(SiMe3C(Ph)C(SiMe3)(C5H4N-2)}] [R) But (2) or CtCPh (3)], respectively. However, the one-pot reaction of 1 with PhC equivalent to CH and (BuLi)-Li-n in Et2O afforded lithium germinate [{(PhC equivalent to C)(3)Ge}(3)GeLi(Et2O)(3)] (4). Compound 1 can also undergo ligand transfer reaction with LiAlH4 to give [AlH{N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)}(2)] (5). Treatment of 1 with excess NaBH4 in THF afforded germanium(II) hydride-borane adduct [Ge(BH3){N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)}H] (6). The reaction of 1 with MI (M) Cu and Au) gave the first examples of Ge(II)- M(I) adducts [Ge(CuI){N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)}Cl](4) (7) and [Ge(AuI){N(SiMe3)C(Ph)C(SiMe3)(C5H4N-2)}Cl] (8). Compounds 2-8 have been characterized by X- ray analysis.

  DOI：

  10.1021/om060032g