glycidyl 4-pentenoate | 117233-47-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: glycidyl 4-pentenoate
• 英文别名: Oxiran-2-ylmethyl pent-4-enoate
• CAS: 117233-47-3
• 化学式: C₈H₁₂O₃
• 分子量: 156.181
• InChiKey: LQAAPVCSEDDMIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  glycidyl 4-pentenoate 在 tin(II) trifluoromethanesulfonate 作用下， 以 乙醇 为溶剂， 反应 8.0h， 以23.08%的产率得到[3-Hydroxy-4-(oxiran-2-ylmethoxy)butyl] pent-4-enoate
  参考文献：
  名称：

  LINEAR POLYESTER AND SEMI-LINEAR GLYCIDOL POLYMER SYSTEMS: FORMULATION AND SYNTHESIS OF NOVEL MONOMERS AND MACROMOLECULAR STRUCTURES

  摘要：

  本文公开了基于环氧丙烷醇的聚合物、纳米粒子及相关的药物传递方法，本摘要旨在作为特定领域搜索的扫描工具，不应限制本发明。

  公开号：

  US20140005278A1
• 作为产物：
  描述：

  allyl 4-pentenoate 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 48.0h， 生成 glycidyl 4-pentenoate
  参考文献：
  名称：

  LINEAR POLYESTER AND SEMI-LINEAR GLYCIDOL POLYMER SYSTEMS: FORMULATION AND SYNTHESIS OF NOVEL MONOMERS AND MACROMOLECULAR STRUCTURES

  摘要：

  本文公开了基于环氧丙烷醇的聚合物、纳米粒子及相关的药物传递方法，本摘要旨在作为特定领域搜索的扫描工具，不应限制本发明。

  公开号：

  US20140005278A1

文献信息

• Epoxy group-containing vinylidene fluoride copolymer and its application to secondary battery
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0751157A1

  公开（公告）日：1997-01-02

  A vinylidene fluoride copolymer having a relatively high molecular weight is formed by copolymerizing (a) vinylidene fluoride as a principal component, (b) a small amount of epoxy group-containing monomer, and (c) an optional component, such as an unsaturated dibasic acid monoester functioning as a curing agent for the epoxy group. When cured with an optional epoxy curing agent, the vinylidene fluoride copolymer provides a cured product having an adhesion with a metal substrate, etc., and also showing excellent solvent resistance and chemical resistance. The vinylidene fluoride copolymer is particularly suitable for constituting a binder for producing an electrode for non-aqueous solvent-type secondary battery.

  一种具有相对较高分子量的偏氟乙烯共聚物是由以下物质共聚而成：(a) 作为主成分的偏氟乙烯；(b) 少量含环氧基的单体；(c) 任选成分，如作为环氧基固化剂的不饱和二元酸单酯。当与任选的环氧固化剂一起固化时，偏氟乙烯共聚物可提供一种与金属基材等具有粘合力的固化产品，同时还具有优异的耐溶剂性和耐化学性。这种偏氟乙烯共聚物尤其适用于构成粘合剂，用于生产非水溶剂型二次电池的电极。
• BASE MATERIAL FILM, LOOSENESS PREVENTION TAPE, AND STORAGE DEVICE
  申请人：Kureha Corporation

  公开号：EP3832768A1

  公开（公告）日：2021-06-09

  A base film is provided that is unlikely to become electrostatically charged. A base film used for a tape for preventing loosening of a wound electrode body, the base film containing a vinylidene fluoride resin as a main component, and the vinylidene fluoride resin containing 1 ppm or greater and less than 12000 ppm of an ionic surfactant relative to a weight of the vinylidene fluoride resin.

  提供了一种不易产生静电的基膜。一种用于防止缠绕电极体松脱的胶带的基膜，该基膜的主要成分是偏氟乙烯树脂，相对于偏氟乙烯树脂的重量，该偏氟乙烯树脂含有 1 ppm 以上、12000 ppm 以下的离子型表面活性剂。
• Linear polyester and semi-linear glycidol polymer systems: formulation and synthesis of novel monomers and macromolecular structures
  申请人：Vanderbilt University

  公开号：US10610598B2

  公开（公告）日：2020-04-07

  Disclosed herein are glycidol-based polymers, nanoparticles, and methods related thereto useful for drug delivery. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

  本文公开了用于给药的缩水甘油基聚合物、纳米颗粒及其相关方法。本摘要旨在作为在特定技术领域进行搜索的扫描工具，并非对本发明的限制。
• POLYSILOXANE BINDER FOR LITHIUM ION BATTERY ELECTRODES
  申请人：Zhang Zhengcheng

  公开号：US20120153219A1

  公开（公告）日：2012-06-21

  An electrode includes a binder and an electroactive material, wherein the binder includes a polymer including a linear polysiloxane or a cyclic polysiloxane. The polymer may be generally represented by Formula I:
• AQUEOUS POLYGLYCIDOL SYNTHESIS WITH ULTRA-LOW BRANCHING
  申请人：Vanderbilt University

  公开号：US20150210805A1

  公开（公告）日：2015-07-30

  Disclosed herein are glycidol-based polymers, nanoparticles, and methods related thereto useful for a variety of applications, including, but not limited to, drug delivery. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.