ethyl-(β-nonyl)alumocyclopentane | 122380-36-3

• 分子结构分类: 有机化合物
• 英文名称: ethyl-(β-nonyl)alumocyclopentane
• 英文别名: 1-ethyl-3-(n-nonyl)alumacyclopentane
• CAS: 122380-36-3
• 化学式: C₁₅H₃₁Al
• 分子量: 238.393
• InChiKey: CRECNPZELSWLHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.26
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  ethyl-(β-nonyl)alumocyclopentane 在 重水 作用下， 生成 1-deuterio-3-deuteriomethyldodecane
  参考文献：
  名称：

  First preparative synthesis of alumocyclopentanes involving zirconium complexes

  摘要：

  DOI：

  10.1007/bf00953739
• 作为产物：
  描述：

  1-十一烯 、 三乙基铝 在 二氯二茂锆 作用下， 以80-95的产率得到ethyl-(β-nonyl)alumocyclopentane
  参考文献：
  名称：

  First preparative synthesis of alumocyclopentanes involving zirconium complexes

  摘要：

  DOI：

  10.1007/bf00953739

文献信息

• Regio- and stereoselective synthesis for a novel class of organoaluminium compounds — substituted aluminacyclopentanes and aluminacyclopentenes assis
  作者：U.M. Dzhemilev、A.G. Ibragimov

  DOI：10.1016/0022-328x(94)88022-0

  日期：1994.2

  A novel regio- and stereoselective method has been developed for the catalytic cyclometallation of olefins and acetylenes with alkylalanes in the presence of Cp(2)ZrCl(2), to give in one stage high yields of 3-substituted aluminacyclopentanes and aluminacyclopentenes. Applications of these reactions to a wide range of linear and cyclic olefins and to those containing functional substituents have been studied. The transformation of the aluminacyclopentanes thus produced, into five-membered heterocycles, mono- and di-substituted cyclobutanes and cyclopropanes, has been demonstrated.
• Synthesis and transformations of metallocycles
  作者：A. G. Ibragimov、L. O. Khafizova、L. G. Yakovleva、E. V. Nikitina、K. G. Satenov、L. M. Khalilov、U. M. Dzhemilev

  DOI：10.1007/bf02496268

  日期：1999.4

  A regioselective method for the synthesis of 3-alkyialumacyclopentanes and 2-alkyl-1,4-dialuminiobutanes by the reactions of alpha-olefins with EtAlCl2, ROAlCl2, R2NAlCl2, or Et2AlCl and the Mg-ClCH2CH2Cl-Cp2ZrCl2 (ZrCl4) system was developed.
• Nontraditional approach to the synthesis of 3-substituted tetrahydrothiophenes and tetrahydroselenophenes
  作者：U. M. Dzhemilev、A. G. Ibragimov、A. P. Zolotarev、G. A. Tolstikov

  DOI：10.1007/bf00957191

  日期：1989.6
• ——
  作者：U. M. Dzhemilev、A. G. Ibragimov、L. O. Khafizova、L. V. Parfenova、D. F. Yalalova、L. M. Khalilov

  DOI：10.1023/a:1012705711678

  日期：——

  The reactions of 3-alkyl-1-ethylalumacyclopentanes with allyl halides in the presence of Ni(acac)(2) as a catalyst were studied by dynamic NMR spectroscopy. Under the action of Ni complexes, alumacyclopentanes initially undergo intramolecular hydride transfer to give but-3-enyl(ethyl)aluminum hydrides and then react with the starting allyl halide, yielding but-3-enyl(ethyl)aluminum halides. Subsequent intramolecular carboalumination affords the corresponding 1,1-disubstituted cyclopropanes.
• DZHEMILEV, U. M.;M.;IBRAGIMOV, A. T.;ZOLOTAREV, A. P.;TOLSTIKOV, T. A., IZV. AN CCCP. CEP. XIM.,(1989) N, S. 1444
  作者：DZHEMILEV, U. M.、M.、IBRAGIMOV, A. T.、ZOLOTAREV, A. P.、TOLSTIKOV, T. A.

  DOI：——

  日期：——