| 192517-40-1

• CAS: 192517-40-1
• 化学式: C₅₉H₇₀P₃Ru*I
• 分子量: 1100.1
• InChiKey: UGTJKZSLARPQTG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ditert-butyl(ethynyl)phosphane;1,2,3,4,5-pentamethylcyclopenta-1,3-diene;ruthenium(2+);triphenylphosphane 、 propyllithium 以 甲苯 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  Ethinylkomplexe des Rutheniums mit terminalen Hauptgruppenelement-Substituenten: Systematischer Aufbau metallgebundener Phosphoniumacetylid-Liganden R′R2P(+)-C≡C|(−)

  摘要：

  Treatment of Cp* RuL2Cl (Cp* = C5Me5; L = PPh3, PMe3) with Me3SiC=C:H in the presence of NH4[PF6] in CH2Cl2 yielded the expected vinylidene compounds [Cp *RuL2=C=CH2][PF6] with L = PPh3 (1) and PMe3 (1a), which were deprotonated by KOBut in THF to give the corresponding ethynyl complexes Cp*Ru(PPh3)(2)C=CH (2) and Cp*Ru(PMe3)(2)C=CH (2a). Metalation of 2 using n-BuLi or t-BuLi in THF-hexane, followed by reaction of the lithio intermediate Cp*Ru(PPh3)(2)C=CLi with CIER3 (E = Si, Ge, Sn) or ClPR2, resulted in the formation of substituted derivatives, Cp*Ru(PPh3)(2)C=CER3 [ER3 = SiMe3 (3), GeMe3 (4), SnBu3n (5)] and Cp*Ru(PPh3)(2)C=CPR2 [PR2 = PPh2 (6), PBu2t (7)] respectively. Quaternization of 6 and 7 by alkyl iodides in toluene smoothly produced phosphonioethynyl complexes, [Cp*Ru(PPh3)(2)C=CPR2R']I [PR2R' = PPh2Me (8), (PBu2Me)-Me-t (9), PPh2Prn (10), (PBu2Prn)-Pr-t(11)], the cations of which may be regarded as donor/acceptor-stabilized derivatives of dicarbon, C-2.

  DOI：

  10.1016/s0022-328x(97)00005-3