N-Dec-9-enyl-acetamid | 2524-54-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-Dec-9-enyl-acetamid
• 英文别名: N-dec-9-enylacetamide
• CAS: 2524-54-1
• 化学式: C₁₂H₂₃NO
• 分子量: 197.321
• InChiKey: AKZUKQYCSJOZDG-UHFFFAOYSA-N

物化性质

• 沸点：
  341.8±21.0 °C(Predicted)
• 密度：
  0.866±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  11-氨基十一酸 在 potassium methanolate 作用下， 以 甲醇 、 溶剂黄146 为溶剂， 生成 N-Dec-9-enyl-acetamid
  参考文献：
  名称：

  Electroorganic Synthesis. 65. Anodic Homocoupling of Carboxylic Acids Derived from Fatty Acids.

  摘要：

  Fatty acid derived carboxylic acids with double bonds, hydroxy-, amino-, keto-, ester- and epoxy groups are anodically coupled to dimers (Kolbe electrolysis) in 29 to 81% yield and up to a 2.5 mol scale. Problems due to the low conductivity of fatty acid salts were overcome by the use of a how cell with a narrow electrode gap. Fatty acids with branched alkyl chains gave dimers with interesting emulsifying properties. Dimethyl hexadecanedioate, accessible from methyl azelate, could be cyclized and further converted into homomuscone and muscone in a few steps. A commercial mixture of dimeric fatty acids (C-36-dicarboxylic acids) has been coupled to give C-70-diesters.

  DOI：

  10.3891/acta.chem.scand.52-0672

文献信息

• Acott,B. et al., Australian Journal of Chemistry, 1968, vol. 21, p. 185 - 195
  作者：Acott,B. et al.

  DOI：——

  日期：——
• Electroorganic Synthesis. 65. Anodic Homocoupling of Carboxylic Acids Derived from Fatty Acids.
  作者：Andreas Weiper-Idelmann、Martin aus dem Kahmen、Hans J. Schäfer、Marianne Gockeln、Per Halfdan Nielsen、Ask Püschl、Kurt V. Mikkelsen、Alexander Senning

  DOI：10.3891/acta.chem.scand.52-0672

  日期：——

  Fatty acid derived carboxylic acids with double bonds, hydroxy-, amino-, keto-, ester- and epoxy groups are anodically coupled to dimers (Kolbe electrolysis) in 29 to 81% yield and up to a 2.5 mol scale. Problems due to the low conductivity of fatty acid salts were overcome by the use of a how cell with a narrow electrode gap. Fatty acids with branched alkyl chains gave dimers with interesting emulsifying properties. Dimethyl hexadecanedioate, accessible from methyl azelate, could be cyclized and further converted into homomuscone and muscone in a few steps. A commercial mixture of dimeric fatty acids (C-36-dicarboxylic acids) has been coupled to give C-70-diesters.