2-amino-6-(4-methoxybenzylideneamino)hexanoic acid | 27759-23-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-amino-6-(4-methoxybenzylideneamino)hexanoic acid
• 英文别名: ε-Anisyliden-lysin
• CAS: 27759-23-5
• 化学式: C₁₄H₂₀N₂O₃
• 分子量: 264.324
• InChiKey: SQYAVWYBXVNUNZ-ZDUSSCGKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  19.0
• 可旋转键数：
  8.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  84.91
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  L-赖氨酸 、 4-甲氧基苯甲醛 以 乙醇 为溶剂， 生成 2-amino-6-(4-methoxybenzylideneamino)hexanoic acid
  参考文献：
  名称：

  de la Moriciere,G.G.; Chatelus,G., Bulletin de la Societe Chimique de France, 1969, p. 4421 - 4425

  摘要：

  DOI：

文献信息

• Schiff's bases derived from l-lysine and aromatic aldehydes as green corrosion inhibitors for mild steel: Experimental and theoretical studies
  作者：Neeraj Kumar Gupta、Chandrabhan Verma、M.A. Quraishi、A.K. Mukherjee

  DOI：10.1016/j.molliq.2015.12.027

  日期：2016.3

  Three Schiffs bases (SBs) namely, 2-amino-6 (2-hydroxybenzelideneamino) hexanoic acid (SB-1), 2-amino-6-(4-methoxybenzelideneamino) hexanoic acid (SB-2) and 2-amino-6-((4-dimethylamino)benzylideneamino) hexanoic acid (SB-3) derived from lysine (amino acid) and three different aldehydes were synthesized and evaluated as corrosion inhibitors for mild steel in 1 M HCl solution using weight loss, electrochemical, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and atomic force microscopy methods. The results showed that inhibition efficiency increases with the increasing concentration. Among the studied SBs the SB-3 showed maximum inhibition efficiency of 95.6% at 400 mg L-1 concentration. Potentiodynamic polarization study revealed that the investigated SBs act as cathodic type inhibitors. Adsorption of the SBs on mild steel surface obeys the Langmuir adsorption isotherms. The weight loss and electrochemical results were well supported by SEM, EDX and AFM analyses. (C) 2015 Elsevier B.V. All rights reserved.