1-bromo-6-[4-(8-bromophenanthren-3-yl)butyl]phenanthrene | 144406-71-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 1-bromo-6-[4-(8-bromophenanthren-3-yl)butyl]phenanthrene
• CAS: 144406-71-3
• 化学式: C₃₂H₂₄Br₂
• 分子量: 568.351
• InChiKey: ZGEMVSAMSOVVNO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.6
• 重原子数：
  34
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  三丁基乙烯基锡 、 1-bromo-6-[4-(8-bromophenanthren-3-yl)butyl]phenanthrene 在 四(三苯基膦)钯 作用下， 以 苯 为溶剂， 以80%的产率得到1-ethenyl-6-[4-(8-ethenylphenanthren-3-yl)butyl]phenanthrene
  参考文献：
  名称：

  1,2-ethano-syn-[2.n](1,6)phenanthrenophanes; First isolated syn-phenanthrenophanes

  摘要：

  The title compounds were prepared by the photocycloaddition of vinylphenanthrene derivatives in 38-49% yields. This method gave syn-phenanthrenophanes exclusively, although other reported methods gave syn- and anti-isomers together. The syn conformation was proved by several spectroscopic methods.

  DOI：

  10.1016/s0040-4039(00)61146-2
• 作为产物：
  描述：

  1,4-bis(4-((E)-2-bromostyryl)phenyl)butane 在 碘 作用下， 以 环己烷 为溶剂， 以20%的产率得到1-bromo-6-[4-(8-bromophenanthren-3-yl)butyl]phenanthrene
  参考文献：
  名称：

  1,2-ethano-syn-[2.n](1,6)phenanthrenophanes; First isolated syn-phenanthrenophanes

  摘要：

  The title compounds were prepared by the photocycloaddition of vinylphenanthrene derivatives in 38-49% yields. This method gave syn-phenanthrenophanes exclusively, although other reported methods gave syn- and anti-isomers together. The syn conformation was proved by several spectroscopic methods.

  DOI：

  10.1016/s0040-4039(00)61146-2