1,3-didecyl-2-methylimidazoliumbis(trifluoromethylsulfonyl)imide | 1310460-36-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1,3-didecyl-2-methylimidazoliumbis(trifluoromethylsulfonyl)imide
• 英文别名: Bis(trifluoromethylsulfonyl)azanide;1,3-didecyl-2-methylimidazol-1-ium
• CAS: 1310460-36-6
• 化学式: C₂F₆NO₄S₂*C₂₄H₄₇N₂
• 分子量: 643.799
• InChiKey: GGZWKSNNSYYYKC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,3-didecyl-2-methylimidazolium chloride 、 bis(trifluoromethane)sulfonimide lithium 以 二氯甲烷 、 水 为溶剂， 以95%的产率得到1,3-didecyl-2-methylimidazoliumbis(trifluoromethylsulfonyl)imide
  参考文献：
  名称：

  Activity Coefficients at Infinite Dilution of Organic Compounds in Four New Imidazolium-Based Ionic Liquids

  摘要：

  Activity coefficients of 42 to 54 organic compounds in the four ionic liquids (ILs) 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate, 1-butyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide, 1,3-didecyl-2-methylimidazolium bis(trifluoromethylsulfonyl)imide, and 1-ethyl-3-methylimidazolium methanesulfonate were measured using inverse gas chromatography from (312 to 353) K. The retention data were also converted to gas-to-IL and water-to-IL partition coefficients using the corresponding gas-to-water partition coefficients. Both sets of partition coefficients were analyzed using the modified Abraham solvation parameter model. The derived equations correlated the experimental gas-to-IL and water-to-IL partition coefficient data to within average standard deviations of 0.113 and 0.143 log units, respectively.

  DOI：

  10.1021/je200195q