(Z)-13-(oxan-2-yloxy)tridec-4-en-2-yn-1-ol | 1048005-48-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (Z)-13-(oxan-2-yloxy)tridec-4-en-2-yn-1-ol
• CAS: 1048005-48-6
• 化学式: C₁₈H₃₀O₃
• 分子量: 294.434
• InChiKey: JYMZGGSVJYKYIH-XQRVVYSFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  21
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (Z)-13-(oxan-2-yloxy)tridec-4-en-2-yn-1-ol 在 manganese(IV) oxide 作用下， 以52%的产率得到(Z)-13-(oxan-2-yloxy)tridec-4-en-2-ynal
  参考文献：
  名称：

  (9Z)-9,13-Tetradecadien-11-ynal, the sex pheromone of the avocado seed moth, Stenoma catenifer

  摘要：

  The highly unsaturated aldehyde (9Z)-9,13-tetradecadien-11-ynal and the corresponding alcohol were identified as possible sex pheromone components of the avocado seed moth, Stenoma catenifer. The aldehyde as a single component attracted more male moths than caged virgin female moths, and addition of the analogous alcohol and/or acetate decreased attraction. A stereospecific synthesis of the pheromone is described. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.06.019
• 作为产物：
  描述：

  (Z)-10-Iodo-1-(2-tetrahydropyranyloxy)-9-decene 、 2-丙炔-1-醇 在 四氢吡咯 、 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 作用下， 以86%的产率得到(Z)-13-(oxan-2-yloxy)tridec-4-en-2-yn-1-ol
  参考文献：
  名称：

  (9Z)-9,13-Tetradecadien-11-ynal, the sex pheromone of the avocado seed moth, Stenoma catenifer

  摘要：

  The highly unsaturated aldehyde (9Z)-9,13-tetradecadien-11-ynal and the corresponding alcohol were identified as possible sex pheromone components of the avocado seed moth, Stenoma catenifer. The aldehyde as a single component attracted more male moths than caged virgin female moths, and addition of the analogous alcohol and/or acetate decreased attraction. A stereospecific synthesis of the pheromone is described. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.06.019