carbamoyl-(2-cyanoacetyl)azanide;2-diphenylphosphanylethyl(diphenyl)phosphane;platinum(2+) | 329015-94-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: carbamoyl-(2-cyanoacetyl)azanide;2-diphenylphosphanylethyl(diphenyl)phosphane;platinum(2+)
• CAS: 329015-94-3
• 化学式: C₃₀H₂₇N₃O₂P₂Pt
• 分子量: 718.591
• InChiKey: KLWCYWRVJVRBQS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] 、 氰乙酰脲 在 triethylamine 作用下， 以 甲醇 为溶剂， 以73%的产率得到carbamoyl-(2-cyanoacetyl)azanide;2-diphenylphosphanylethyl(diphenyl)phosphane;platinum(2+)
  参考文献：
  名称：

  Synthesis and characterisation of four-membered ring platinalactam complexes derived from 2-cyanoacetylurea; crystal structure of [H(CN)}(PPh3)2]

  摘要：

  The reactions of cis-[PtCl2L2] [L = PPh3 or L-2 = dppe (Ph2PCH2CH2PPh2)] with cyanoacetylurea [NCCH2C(O)NHC(O)NH2] and triethylamine gives the platinalactam complexes [Pt{N(CONH2)C(O)CH(CN)}L-2]. A single-crystal X-ray diffraction study on the triphenylphosphine complex confirms the presence of the four-membered platinalactam ring; the urea substituent is involved in intra- and intermolecular hydrogen bonding, forming a dimer in the solid state. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00237-1