(2-(2,5-di-tert-butylphenyl)-1,3-dioxo-2,3-dihydro-1H-benzo[10,5]anthra[2,1,9-def]isoquinolin-8-yl)(nitrooxy)bis(triethyl-l5-phosphaneyl)platinum | 1250889-96-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: (2-(2,5-di-tert-butylphenyl)-1,3-dioxo-2,3-dihydro-1H-benzo[10,5]anthra[2,1,9-def]isoquinolin-8-yl)(nitrooxy)bis(triethyl-l5-phosphaneyl)platinum
• CAS: 1250889-96-3
• 化学式: C₄₈H₆₀N₂O₅P₂Pt
• 分子量: 1002.04
• InChiKey: FYKUXHGESMJZIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  六氟磷酸钾 、 异氰酸叔丁酯 、 (2-(2,5-di-tert-butylphenyl)-1,3-dioxo-2,3-dihydro-1H-benzo[10,5]anthra[2,1,9-def]isoquinolin-8-yl)(nitrooxy)bis(triethyl-l5-phosphaneyl)platinum 以 水 、 丙酮 为溶剂， 以79%的产率得到[Pt(tert-butylisocyanide)(C22H9O2NC6H3-t-Bu2)(PEt3)2]PF6
  参考文献：
  名称：

  Highly Fluorescent Platinum(II) Organometallic Complexes of Perylene and Perylene Monoimide, with Pt σ-Bonded Directly to the Perylene Core

  摘要：

  3-Bromoperylene (BrPer) or N-(2,5-di-tert-butylphenyl)-9-bromo-perylene-3,4-dicarboximide (BrPMI) react with [Pt(PEt3)(4)] to yield trans-[PtR(PEt3)(2)Br] (R = Per, la; R = PMI, lb). Neutral and cationic perylenyl complexes containing a Pt(PEt3)X group have been prepared from la,b by substitution of the Br ligand by a variety of other ligands (NCS, ON, NO3, (CNBu)-Bu-t, PyMe). The X-ray structures of trans-[PtR(PEt3)(2)X] (R = Per, X = NCS (2a); R = PMI, X = NO3 (4b); R = Per, X = (CNBu)-Bu-t (5a)) show that the perylenyl fragment remains nearly planar and is arranged almost orthogonal to the coordination plane: The three molecules appear as individual entities in the solid state, with no pi-pi stacking of perylenyl rings. Each platinum complex exhibits fluorescence associated to the perylene or PMI fragments with emission quantum yields, in solution at room temperature, in the range 0.30-0.80 and emission lifetimes similar to 4 ns, but with significantly different emission maxima, by influence of the X ligands on Pt. The similarity of the overall luminescence spectra of these metalated complexes with the perylene or PMI strongly suggests a perylene-dominated intraligand pi-pi(star) emissive state, metal-perturbed by interaction of the platinum fragment mostly via polarization of the Ar-Pt bond.

  DOI：

  10.1021/ic1003319
• 作为产物：
  描述：

  、 silver nitrate 以 丙酮 为溶剂， 以86%的产率得到(2-(2,5-di-tert-butylphenyl)-1,3-dioxo-2,3-dihydro-1H-benzo[10,5]anthra[2,1,9-def]isoquinolin-8-yl)(nitrooxy)bis(triethyl-l5-phosphaneyl)platinum
  参考文献：
  名称：

  Highly Fluorescent Platinum(II) Organometallic Complexes of Perylene and Perylene Monoimide, with Pt σ-Bonded Directly to the Perylene Core

  摘要：

  3-Bromoperylene (BrPer) or N-(2,5-di-tert-butylphenyl)-9-bromo-perylene-3,4-dicarboximide (BrPMI) react with [Pt(PEt3)(4)] to yield trans-[PtR(PEt3)(2)Br] (R = Per, la; R = PMI, lb). Neutral and cationic perylenyl complexes containing a Pt(PEt3)X group have been prepared from la,b by substitution of the Br ligand by a variety of other ligands (NCS, ON, NO3, (CNBu)-Bu-t, PyMe). The X-ray structures of trans-[PtR(PEt3)(2)X] (R = Per, X = NCS (2a); R = PMI, X = NO3 (4b); R = Per, X = (CNBu)-Bu-t (5a)) show that the perylenyl fragment remains nearly planar and is arranged almost orthogonal to the coordination plane: The three molecules appear as individual entities in the solid state, with no pi-pi stacking of perylenyl rings. Each platinum complex exhibits fluorescence associated to the perylene or PMI fragments with emission quantum yields, in solution at room temperature, in the range 0.30-0.80 and emission lifetimes similar to 4 ns, but with significantly different emission maxima, by influence of the X ligands on Pt. The similarity of the overall luminescence spectra of these metalated complexes with the perylene or PMI strongly suggests a perylene-dominated intraligand pi-pi(star) emissive state, metal-perturbed by interaction of the platinum fragment mostly via polarization of the Ar-Pt bond.

  DOI：

  10.1021/ic1003319