(5,15-diphenyl-2,8,12,18-tetra-n-butyl-3,7,13,17-tetramethylporphyrinato)zinc | 131906-54-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: (5,15-diphenyl-2,8,12,18-tetra-n-butyl-3,7,13,17-tetramethylporphyrinato)zinc
• 英文别名: [2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-diphenylporphyrinato]zinc；zinc 2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-diphenylporphyrinate；zinc 2,8,12,18-tetrabutyl-5,15-diphenyl-3,7,13,17-tetramethylporphyrinate；[Zn(5,15-diphenyltetramethyltetrabutylporphyrine)]
• CAS: 131906-54-2
• 化学式: C₅₂H₆₀N₄Zn
• 分子量: 806.465
• InChiKey: AIJFSKNBPPCHQK-VEDQQJGDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.93
• 重原子数：
  57.0
• 可旋转键数：
  14.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  34.58
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  (5,15-diphenyl-2,8,12,18-tetra-n-butyl-3,7,13,17-tetramethylporphyrinato)zinc 在 溶剂黄146 作用下， 以 苯 为溶剂， 生成 zinc diacetate 、 2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-diphenylporphyrin
  参考文献：
  名称：

  Mamardashvili, N. Zh.; Klopova, L. V.; Golubchikov, O. A., Russian Journal of Coordination Chemistry, 1994, vol. 20, p. 63 - 65

  摘要：

  DOI：
• 作为产物：
  描述：

  zinc diacetate 、 2,8,12,18-tetrabutyl-3,7,13,17-tetramethyl-5,15-diphenylporphyrin 以 乙腈 为溶剂， 生成 (5,15-diphenyl-2,8,12,18-tetra-n-butyl-3,7,13,17-tetramethylporphyrinato)zinc
  参考文献：
  名称：

  摘要：

  Kinetics of interaction of diphenyl-substituted porphyrins and their derivatives with substituents in the phenyl fragments with zinc acetate in acetonitrile solution is studied. The effect of the solvent on the rate of coordination is shown. Kinetic parameters of complexation are calculated.

  DOI：

  10.1023/a:1023300404659

文献信息

• A Cyclic Porphyrin Trimer as a Receptor for Fullerenes
  作者：Guzmán Gil-Ramírez、Steven D. Karlen、Atsuomi Shundo、Kyriakos Porfyrakis、Yasuhiro Ito、G. Andrew D. Briggs、John J. L. Morton、Harry L. Anderson

  DOI：10.1021/ol101393h

  日期：2010.8.6

  A cyclic porphyrin trimer has been synthesized which has a high affinity for fullerenes. It forms 1:1 complexes with C60 and C70 with association constants of 2 × 106 and 2 × 108 M−1, respectively, in toluene. Its affinities for C86 and [email protected]82 are too strong to measure by fluorescence titration. The solvent dependence of the association constants shows that solvation of both the guest

  已经合成了对富勒烯具有高亲和力的环状卟啉三聚体。它在甲苯中分别与C 60和C 70形成1：1配合物，缔合常数分别为2×10 6和2×10 8 M -1。它对C 86和[电子邮件保护的] 82的亲和力太强，无法通过荧光滴定法进行测量。缔合常数对溶剂的依赖性表明，客体和主体的溶剂化都会影响结合强度。
• Molecular recognition of α-amino acid esters with arylporphyrin zinc complexes
  作者：G. M. Mamardashvili、O. E. Storonkina、N. Zh. Mamardashvili

  DOI：10.1007/s11176-005-0029-0

  日期：2004.9

  The recognition ability of 10 arylporphyrin zinc complexes with respect to glycine, α-alanine, and leucine methyl esters in toluene at 20°C was studied by spectrophotometric titration. The formation of amino acid-porphyrin associates, depending on the substitution pattern in the macroring, was examined by 1H NMR spectroscopy. The zinc complex with diarylporphyrin having hydroxy groups in the para positions of the benzene rings was found to be the best recognizing agent with respect to glycine methyl ester, while leucine methyl ester was recognized best by the complex with hydroxy groups in the ortho positions of the benzene rings.

  采用分光光度滴定法研究了20℃甲苯中10种芳基卟啉锌配合物对甘氨酸、α-丙氨酸和亮氨酸甲酯的识别能力。氨基酸-卟啉缔合体的形成取决于大环中的取代模式，通过 1 H NMR 光谱进行检查。发现苯环对位具有羟基的二芳基卟啉的锌络合物对于甘氨酸甲酯是最好的识别剂，而苯环邻位具有羟基的二芳基卟啉的锌络合物对亮氨酸甲酯的识别效果最好。苯环。
• Supramolecular complexes of carboxy-substituted zinc porphyrinates with triethylenediamine
  作者：G. M. Mamardashvili、O. M. Kulikova、O. I. Koifman

  DOI：10.1134/s1070363208100253

  日期：2008.10

  alpha, alpha- and alpha,beta-Atropoisomers of zinc 5,15-bis(2-carboxyphenyl) octaalkylporphyrinate were obtained, and their complex formation with triethylenediamine in toluene was studied. The alpha, alpha-atropoisomer is present in the solution as a supramolecular dimer and forms a 1:1 complex with the two-centered nitrogen-containing base. The complex formation of the undimerized alpha, beta-atropoisomer with triethylenediamine can give 2:1 or 1:1 complexes, depending on the reagent ratio. The stability constants of the complexes and the concentration ranges of their formation were determined by means of spectrophotometric titration and H-1 NMR spectroscopy.
• Complexation of Zn Arylporphyrinates with Leucine Methyl Ester
  作者：G. M. Mamardashvili、O. E. Storonkina、N. Zh. Mamardashvili

  DOI：10.1023/b:ruco.0000030157.98943.43

  日期：2004.6

  Extra coordination of L-leucine methyl ester with seventeen different Zn arylporphyrinates is studied by spectrophotometric titration and capability of Zn porphyrinates with the active OH groups to recognize LeiOCH(3) in toluene at 20degreesC is determined. The formation of associates of the composition amino acid etherporphyrinate depending on the substituent positions in a macrocycle is studied by the H-1 NMR method. The most strong donor-acceptor bonds between Zn porphyrinate and LeiOCH(3) are observed in the case of pyridine-substituted porphyrins and porphyrins with phenyl rings containing electron-donor substituents in the m-position. The best recognizing capabilities with respect to leucine are shown by Zn porphyrinates with di- and tetra-4-OH-phenyl substitution in the meso-positions of a macrocycle.