cis-dichloridobis(2-methyl-2H-tetrazol-5-amine-κN**(4))platinum(II) | 1322697-26-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: cis-dichloridobis(2-methyl-2H-tetrazol-5-amine-κN**(4))platinum(II)
• 英文别名: 2-methyltetrazol-5-amine;platinum(2+);dichloride
• CAS: 1322697-26-6
• 化学式: C₄H₁₀Cl₂N₁₀Pt
• 分子量: 464.176
• InChiKey: VXXVRCWWQPDVAE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -8.41
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  139
• 氢给体数：
  2
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2-甲基-5-氨基-2H-四氮唑 、 potassium tetrachloroplatinate(II) 以 盐酸 为溶剂， 以82%的产率得到cis-dichloridobis(2-methyl-2H-tetrazol-5-amine-κN**(4))platinum(II)
  参考文献：
  名称：

  An X-ray powder diffraction study ofcis-dichloridobis(2-methyl-2H-tetrazol-5-amine-κN⁴)platinum(II), a tetrazole-containing analogue of cisplatin

  摘要：

  The structure of the title compound, cis-[PtCl2(C2H5N5)(2)], was analysed using in-house X-ray powder diffraction data at room temperature. The structure was solved by direct methods and refined using Rietveld analysis. A slightly distorted square-planar coordination geometry is formed around the Pt atom by two Cl atoms and two ring N atoms of the 2-methyl-2H-tetrazol-5-amine ligands, which are in a cis configuration. The planes of the tetrazole rings are inclined at 79.7 (7) and 73.8 (6)degrees with respect to the coordination plane, with their substituents oriented in such a way that the complex as a whole has approximate C-2 symmetry. Intermolecular N-H center dot center dot center dot Cl hydrogen bonds mediate the formation of a three-dimensional supramolecular network.

  DOI：

  10.1107/s0108270111018063