(tetra-n-butyl-ammonium)3(tetra(oxodiperoxotungstato)phosphate) | 92924-16-8

• 分子结构分类: 有机化合物
• 英文名称: (tetra-n-butyl-ammonium)3(tetra(oxodiperoxotungstato)phosphate)
• 英文别名: tris(tetrabutylammonium) tetrakis(oxodiperoxotungsto)phosphate；[(Buⁿ)₄N]₃{PO₄[WO(O₂)₂]₄}；[Bu4N]3{PO4[WO(O2)2]4}；(BuN)3[(W(O)(O2)2)4(μ-PO4)]
• CAS: 92924-16-8
• 化学式: 3C₁₆H₃₆N*O₂₄PW₄
• 分子量: 1877.76
• InChiKey: FSVSAODVKMTYCO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四丁基硫酸氢铵 、 ortho-tungstic acid 在 磷酸 、 双氧水 作用下， 以 水 为溶剂， 生成 (tetra-n-butyl-ammonium)3(tetra(oxodiperoxotungstato)phosphate)
  参考文献：
  名称：

  Aubry, Catherine; Chottard, Geneviève; Platzer, Nicole, Inorganic Chemistry, 1991, vol. 30, # 23, p. 4409 - 4415

  摘要：

  DOI：
• 作为试剂：
  描述：

  辛醇 在 (tetra-n-butyl-ammonium)3(tetra(oxodiperoxotungstato)phosphate) 、 双氧水 作用下， 以 水 为溶剂， 反应 3.0h， 以65%的产率得到辛酸
  参考文献：
  名称：

  Structure and properties of tungsten peroxopolyoxo complexes – Promising catalysts for organics oxidation. I. Structure of peroxocomplexes studied during the stepwise synthesis of tetra(diperoxotungsten)phosphate-tetra-n-butyl ammonium

  摘要：

  Catalysis via metal complexes has been studied using EXAFS and Raman spectroscopy. Main polyoxo- and peroxopolyoxocomplexes of tungsten, resulting from the interaction of phosphorus tungsten heteropolyacid with hydrogen peroxide in water solutions, were investigated with regard to their form and structure. Interaction was shown to reduce the nuclearity of forming complexes with respect to their precursor - H3PW12O40. The symmetry of oxygen environment of tungsten was found to change, distances W-W remaining the same. After complex [(Bu4N)-N-n](3) {PO4[WO(O-2)(2)](4)} is isolated, binuclear anion [W2O3(O-2)(4)(H2O2)](2-) stays in the solution. Raman scattering, EXAFS and IR spectroscopy show that isolated peroxocomplex in its crystal state has four nuclei, and most probably retains this structure being dissolved in acetonitrile.Synthesized catalytic complex [(Bu4N)-N-n](3){PO4[WO(O-2)(2)](4)} was tested in oxidation of cyclic alkenes and alcohols with hydrogen peroxide. Complex [(Bu4N)-N-n](3){PO4[WO(O-2)(2)](4)} was proved to provide higher yields of mono- and dicarbonic acids in comparison to in situ synthesized catalyst. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2010.09.007

文献信息

• Selective epoxidation of cyclohexene to cyclohexene oxide catalyzed by Keggin-type heteropoly compounds using anhydrous urea–hydrogen peroxide as oxidizing reagent and acetonitrile as the solvent
  作者：Yong Ding、Qiang Gao、Guixian Li、Hanpeng Zhang、Jianmin Wang、Liang Yan、Jishuan Suo

  DOI：10.1016/j.molcata.2004.04.019

  日期：2004.8

  The epoxidation of cyclohexene catalyzed by Keggin-type heteropoly compounds (HPAs) were investigated using anhydrous urea–hydrogen peroxide adduct (UHP) as an oxidant and acetonitrile as a solvent. Among a series of Keggin-type heteropoly compounds, tris(cetylpyridinium)12-tungstophosphate (CWP) showed the highest activity. By optimizing the reaction conditions, 80% conversion of cyclohexene and 97%

  以无水尿素-过氧化氢加合物（UHP）为氧化剂，以乙腈为溶剂，研究了Keggin型杂多化合物（HPA）催化的环己烯环氧化。在一系列Keggin型杂多化合物中，三（十六烷基吡啶）12-钨磷酸盐（CWP）表现出最高的活性。通过优化反应条件，可以在UHP / CH 3 CN系统中实现80％的环己烯转化率和97％的环己烯氧化物选择性。当使用30％的过氧化氢水溶液（H 2 O 2，HP）时，环己烯的转化率和环己烯的环氧选择性不如UHP / CH 3 CN系统。UHP与CWP的反应已通过UV-Vis和 NMR光谱显示，在过量的UHP存在下，Keggin型杂多化合物CWP会降解，形成大量的含磷物质。
• TUNGSTEN PEROXOPOLYOXO COMPLEXES ARE PROSPECTIVE CATALYSTS FOR THE OXIDATION OF ORGANIC COMPOUNDS. I.  STRUCTURE OF COMPLEX [(BUn)4N]3{PO4[WO(O2)2]4} ACCORDING TO SMALL-ANGLE X-RAY SCATTERING
  作者：Yu. V. Larichev、N. V. Selivanova、P. V. Berdnikova、F. V. Tuzikov、Z. P. Pai

  DOI：10.1134/s002247662010008x

  日期：2020.10

  The structure of the H3PW12O40 oxometalate precursor and that of the [(Bun)4N]3PO4[WO(O2)2]4} peroxo complex which was synthesized from it are studied by small-angle X-ray scattering (SAXS) in solutions. It is shown that the structure of H3PW12O40 is partially destroyed as a result of the interaction with hydrogen peroxide to form the PO4[WO(O2)2]4}3– anion. The synthesized peroxo complex [(Bun)4N]3PO4[WO(O2)2]4}

  H3PW12O40 金属氧酸盐前体的结构和由它合成的 [(Bun)4N]3PO4[WO(O2)2]4} 过氧配合物的结构通过小角 X 射线散射 (SAXS) 在解决方案。结果表明，由于与过氧化氢相互作用形成 PO4[WO(O2)2]4}3- 阴离子，H3PW12O40 的结构被部分破坏。合成的过氧复合物 [(Bun)4N]3PO4[WO(O2)2]4} 在甲苯中作为单个分子出现，而其分子在乙腈溶液中部分聚集形成 1.6 nm 颗粒。