1-[3-(methacryloyloxy)propyl]-3-methylimidazolium bis(trifluoromethylsulfonyl)imide | 1189112-86-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-[3-(methacryloyloxy)propyl]-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
• 英文别名: 1-[2-(methacryloyloxy)propyl]-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
• CAS: 1189112-86-4
• 化学式: C₂F₆NO₄S₂*C₁₁H₁₇N₂O₂
• 分子量: 489.417
• InChiKey: GYAANSOTAHLEGD-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1-(3-hydroxypropyl)-3-methylimidazolium bis(trifluoromethanesulfonyl)imide 、 甲基丙烯酰氯 反应 18.5h， 以66%的产率得到1-[3-(methacryloyloxy)propyl]-3-methylimidazolium bis(trifluoromethylsulfonyl)imide
  参考文献：
  名称：

  聚合离子液体：聚阳离子和聚阴离子的比较

  摘要：

  在新型“聚合离子液体”（PIL）中实现高离子电导率引起了极大的兴趣，因为它涉及固态电解质及其在电化学中的应用。四个离子单体，包括两个新的离子单体，即N -[（2-甲基丙烯酰氧基）-丙基] -N-甲基吡咯烷鎓双（三氟甲基磺酰基）酰胺（M1），1- [2-（甲基丙烯酰氧基）丙基] -3-甲基咪唑双（三氟甲基磺酰基）酰胺（M2），N-甲基-N-乙基吡咯烷鎓（3-磺丙基）甲基丙烯酸酯（M3）和1-甲基-3-乙基咪唑鎓（3-磺丙基）甲基丙烯酸酯（M4制备），并将其用于合成线性PIL和与聚（乙二醇）二甲基丙烯酸酯（PEGDM）的离子网络。获得高摩尔质量PIL（M sD高达1.24×10 6）的最佳聚合条件（g / mol）。还研究了带相反电荷的单体的共聚。对聚阳离子，聚阴离子及其无规离子共聚物的物理性质进行了比较。发现所检查的性质主要取决于抗衡离子的性质。显而易见的是，亲水性聚阴离子的整体离子电导率受

  DOI：

  10.1021/ma2014518

文献信息

• Bis(trifluoromethylsulfonyl)amide based “polymeric ionic liquids”: Synthesis, purification and peculiarities of structure–properties relationships
  作者：Alexander S. Shaplov、Elena I. Lozinskaya、Denis O. Ponkratov、Inna A. Malyshkina、Frederic Vidal、Pierre-Henri Aubert、Ol’ga V. Okatova、George M. Pavlov、Lidiya I. Komarova、Christine Wandrey、Yakov S. Vygodskii

  DOI：10.1016/j.electacta.2011.06.041

  日期：2011.12

  A series of bis(trifluoromethylsulfonyl)amide based "polymeric ionic liquids" (PILs) as high molecular mass analogues of the corresponding imidazolium, ammonium and pyrrolidinium ionic liquids (ILs) was synthesized with high purity and fully characterized including electrochemical properties. The PILs differed by the nature of the cation, the quantity of the ionic centers in each monomer repeating unit, and the alkyl length of the spacer. Two novel ionic liquid like monomers (ILMs), namely 1,3-bis(N,N,N-trimethylammonium)-2-propylmethacrylate bis(trifluoromethylsulfonyl) amide (ILM-2) and N-[(2-methacryloyloxy)-ethyl]-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (ILM-4) were synthesized and characterized. Optimal conditions for the free-radical polymerization of the ILMs were identified for the first time. It was demonstrated that, among the tested organic solvents, 1-methyl-3-ethylimidazolium bis(trifluoromethylsulfonyl)amide IL was the best reaction medium in terms of the achievement of high polymer yields and molecular masses. For the first time, the influence of the residual monomer presence inside the PIL film on the resultant conductivity was clearly shown. The impact of the molecular mass of the PILs on the ionic conductivity was firstly studied as well. Finally, the copolymerization of ILMs with poly(ethylene glycol)dimethacrylate (PEGDM) was carried out yielding tight elastic films with the highest conductivity equal to 3.2 x 10(-6) S/cm at 25 degrees C. (C) 2011 Elsevier Ltd. All rights