Mn(OAc)(5,10,15,20-tetraphenyloctaethylporphyrin) | 622832-67-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Mn(OAc)(5,10,15,20-tetraphenyloctaethylporphyrin)
• CAS: 622832-67-1
• 化学式: C₆₂H₆₃MnN₄O₂
• 分子量: 951.146
• InChiKey: GYEBVIZNASWGGO-BPMCWUKLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  manganese triacetate 、 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin 以 N,N-二甲基甲酰胺 为溶剂， 生成 Mn(OAc)(5,10,15,20-tetraphenyloctaethylporphyrin)
  参考文献：
  名称：

  摘要：

  Octaethyl-, 5-phenyloctaethyl-, 5,15-diphenyloctaethyl-, 5,10,15,20-tetraphenyloctaethyl, and dodecaphenylporphyrins were prepared, and their geometries were optimized by the method of molecular mechanics. The deformation of the porphyrin macroring grows as the number of phenyl groups is increased. The dissociation kinetics of the manganese, cobalt, and copper complexes of the porphyrins in solutions of sulfuric acid in acetic acid were studied. The kinetic parameters of the dissociation of metal porphyrins were analyzed in relation to the porphyrin structure and nature of the metal.

  DOI：

  10.1023/a:1025673427341