| 1020732-65-3

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• CAS: 1020732-65-3
• 化学式: C₃N₃
• 分子量: 78.0531
• InChiKey: FGXGUHMKUYYJJF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.73
• 重原子数：
  6.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.67
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  以 solid 为溶剂， 生成
  参考文献：
  名称：

  About a new class of inorganic polymers: the polythiocyanogens [Sz(CN)2]x

  摘要：

  It is shown that all the pseudohalogens belonging to the series of sulfur dicyanide S-y (CN)(2) or thiocyanogens polymerise very easily in the dry state, under moderate heating to produce a series of brick-red or orange solids known as polythiocyanogens with the general formula [S-y(CN)(2)](x) with y an integer 1, 2, 3, 4. It is shown by FT-IR, electronic spectroscopy, and C-13 NMR spectroscopy that the structure of all the series is essentially the same. The use of model compounds with 1,3,5-triazine structure and of particular reactions with Na2S and NaCN reveal that the [S-y(CN)(2)](x) polymers have essentially a polyazomethine chain analogous to that of polycyanogen or paracyanogen (CN), but crosslinked with sulfur bridges of different length depending on the sulfur chain length in the original monomer. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01060-4