Organic thiosulphates and thiosulphonates useful as stabilising agents for rubber vulcanisates
申请人:MONSANTO EUROPE S.A.
公开号:EP0070143A1
公开(公告)日:1983-01-19
Additives for rubber compositions, giving vulcanisates having improved retention of optimum physical properties, are compounds containing two or more groups of the formula -S-S02R linked by an organic bridging group, or polymers containing two or more groups of the formula -S-S02R attached to an organic polymer chain, where R represents (a) a radical OM where M is a monovalent metal, the equivalent of a multivalent metal, a monovalent ion derived by the addition of a proton to a nitrogenous base, or the equivalent of a multivalent ion derived by the addition of two or more protons to a nitrogenous base, or (b) an organic radical selected from aliphatic, cycloaliphatic, aromatic and heterocyclic radicals, and radicals which are combinations of any two or more such radicals.
用于橡胶组合物的添加剂,使硫化胶能更好地保持最佳物理性能,这些添加剂是含有两个或两个以上由有机桥基连接的式-S-S02R 的化合物,或含有两个或两个以上连接到有机聚合物链上的式-S-S02R 的聚合物,其中 R 代表 (a) 自由基 OM,其中 M 是一价金属、(b) 选自脂肪族、环脂族、芳香族和杂环族的有机自由基,以及由任意两个或多个此类 自由基组合而成的自由基。