N-allyl-2-vinylaniline | 1510778-95-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-allyl-2-vinylaniline
• 英文别名: allyl(2-vinylphenyl)amine；n-Allyl-o-vinylaniline；2-ethenyl-N-prop-2-enylaniline
• CAS: 1510778-95-6
• 化学式: C₁₁H₁₃N
• 分子量: 159.231
• InChiKey: GMIJBACUOUQMKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-allyl-2-vinylaniline 在 碘 、 氧气 、 2-碘酰基苯甲酸 作用下， 以 二甲基亚砜 为溶剂， 反应 15.0h， 以72%的产率得到1-烯丙基-1H-吲哚-2,3-二酮
  参考文献：
  名称：

  Iodine-Mediated C–H Functionalization of sp, sp², and sp³ Carbon: A Unified Multisubstrate Domino Approach for Isatin Synthesis

  摘要：

  Molecular iodine-promoted efficient construction of isatins from 2'-aminophenylacetylenes, 2'-aminostyrenes, and 2'-amino-,beta-ketoesters is developed via oxidative amidation of sp, sp(2), and sp(3) C-H bonds. The reaction involves consecutive iodination, Kornblum oxidation, and intramolecular amidation in a single reactor. The present method meets all of the atom and redox economy principles.

  DOI：

  10.1021/acs.joc.5b00581
• 作为产物：
  描述：

  2-溴苯乙烯 、 丙烯胺 在 2-(二叔丁基膦)联苯 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以81%的产率得到N-allyl-2-vinylaniline
  参考文献：
  名称：

  A Convergent, Modular Approach to Functionalized 2,1-Borazaronaphthalenes from 2-Aminostyrenes and Potassium Organotrifluoroborates

  摘要：

  Azaborines are an important class of compounds with applications in both medicinal chemistry and materials science. The first borazaronaphthalene, 2-chloro-2,1-borazaronaphthalene, was reported in 1959; however, access to more highly functionalized substructures has been limited because of the harsh reaction conditions required to displace the chloride on boron. A convergent approach has been developed to synthesize disubstituted 2,1-borazaronaphthalenes from N-substituted 2-aminostyrenes and potassium organotrifluoroborates, where the potassium organotrifluoroborate is converted to the active R-BX2 species (X = Cl or F) in situ by addition of a fluorophile. Starting from aryl-, heteroaryl-, alkynyl-, alkenyl-, and alkyltrifluoroborates, a library of highly functionalized 2,1-borazaronaphthalenes were synthesized in one step under mild, transition-metal-free conditions.

  DOI：

  10.1021/jo402616w

文献信息

• Triggered response compositions
  申请人：Rohm and Haas

  公开号：EP1386959A1

  公开（公告）日：2004-02-04

  This invention provides a triggered response composition in the form of a barrier material and a delivery device that includes one or more polyelectrolytes in contact with an aqueous system that is stable and insoluble in a liquid medium and that exhibits one or more chemical/physical responses in the liquid medium, wherein the chemical/physical response of the composition is triggered upon a change of ionic strength in the liquid medium.

  本发明提供了一种阻隔材料和递送装置形式的触发响应组合物，它包括一种或多种与水性体系接触的聚电解质，在液体介质中稳定且不溶解，并在液体介质中表现出一种或多种化学/物理响应，其中组合物的化学/物理响应是在液体介质中离子强度发生变化时触发的。
• ION EXCHANGE BODY AND PRODUCTION METHOD THEREFOR
  申请人：Astom Corporation

  公开号：EP2412751A1

  公开（公告）日：2012-02-01

  [Problems] To provide an ion exchanger having excellent electric properties, a low electric resistance, excellent mechanical strength and, at the same time, having excellent contamination resistance. [Means for Solution] An ion exchanger comprises a melt-extrusion-formed body of a resin composition containing a granular ion-exchange resin and a low-melting polyolefin resin having a melting point of not higher than 170°C, the melt-extrusion-formed body: (a) containing the granular ion-exchange resin at a ratio of not less than 30% by weight but less than 50% by weight, and the low-melting polyolefin resin in an amount of more than 100 parts by weight but not more than 150 parts by weight per 100 parts by weight of the granular ion-exchange resin; (b) having a melt index in a range of 1 to 5 g/10 min. as measured at 190°C; and (c) having a water content of not less than 30%.

  [问题]提供一种电性能优异、电阻低、机械强度高，同时抗污染能力强的离子交换器。 [解决方法] 一种离子交换器包括由树脂组合物熔融挤压成型的主体，该树脂组合物含有颗粒状离子交换树脂和熔点不高于 170°C 的低熔点聚烯烃树脂，熔融挤压成型的主体：(a) 粒状离子交换树脂的重量比不小于 30%但不小于 50%，低熔点聚烯烃树脂的重量比大于 100 份但不大于 150 份； (b) 熔体指数范围为 1 至 5 克/10 分钟（在 190℃下测量）；以及 (c) 低熔点聚烯烃树脂的重量比大于 100 份但不大于 150 份。(c) 含水量不低于 30%。
• GEL MATERIAL
  申请人：National University Corporation Hokkaido University

  公开号：EP3828225A1

  公开（公告）日：2021-06-02

  Disclosed is a gel material having a high water content and excellent mechanical properties. The gel material includes repeating units derived from the following monomers (A) and (B): (A) an anionic monomer containing a polymerizable carbon-carbon multiple bond and an aromatic ring, and (B) a cationic monomer containing a polymerizable carbon-carbon multiple bond and an aromatic ring. The gel material has a water content of 20% by mass to 95% by mass, a tensile elastic modulus of 9 MPa to 1000 MPa, and a tensile elongation at break of 50% to 5000%.

  本发明公开了一种具有高含水量和优异机械性能的凝胶材料。该凝胶材料包括由以下单体（A）和（B）衍生的重复单元：（A）含有可聚合碳-碳多键和芳香环的阴离子单体，以及（B）含有可聚合碳-碳多键和芳香环的阳离子单体。凝胶材料的含水量为 20% 至 95%，拉伸弹性模量为 9 兆帕至 1000 兆帕，拉伸断裂伸长率为 50% 至 5000%。
• Accessing an Azaborine Building Block: Synthesis and Substitution Reactions of 2-Chloromethyl-2,1-borazaronaphthalene
  作者：Gary A. Molander、Steven R. Wisniewski、Javad Amani

  DOI：10.1021/ol502708z

  日期：2014.11.7

  One major synthetic route to the synthesis of benzyl amines, ethers, and esters is the nucleophilic substitution of a benzylic halide. To develop a method for the facile synthesis and functionalization of the isosteric azaborines, 2-chloromethyl-2,1-borazaronaphthalene has been synthesized in one step to afford a similar common precursor to a benzylic halide. This BN isostere has been shown to be an effective building block by serving as an electrophile in substitution reactions with a large variety of nucleophiles.
• Method for Accessing Nitrogen-Containing, <i>B</i>-Heteroaryl-Substituted 2,1-Borazaronaphthalenes
  作者：Geraint H. M. Davies、Zhao-Zhao Zhou、Matthieu Jouffroy、Gary A. Molander

  DOI：10.1021/acs.joc.6b02574

  日期：2017.1.6

  The azaborine motif provides a mimic of aromatic systems through replacement of a C═C bond with a B-N bond. In particular, 2,1-borazaronaphthalenes, accessible through robust methods of synthesis and subsequent functionalization, afford an ideal platform to use for a variety of applications. However, the scope of substructures for this archetype has been limited by the lack of nitrogen-containing heteroaryls that can be incorporated within them. In this study, modified reaction conditions were developed to provide access to a wider range of substructures.