benzene;1-[3-[(dimethylamino)methyl]benzene-2-id-1-yl]-N,N-dimethylmethanamine;tin(4+);trifluoromethanesulfonate | 1042157-59-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: benzene;1-[3-[(dimethylamino)methyl]benzene-2-id-1-yl]-N,N-dimethylmethanamine;tin(4+);trifluoromethanesulfonate
• CAS: 1042157-59-4
• 化学式: C₂₀H₂₄F₆N₂O₆S₂Sn
• 分子量: 685.253
• InChiKey: MPGKUVJMVVMTCJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.82
• 重原子数：
  37
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  138
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  benzene;1-[3-[(dimethylamino)methyl]benzene-2-id-1-yl]-N,N-dimethylmethanamine;tin(4+);trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以77%的产率得到
  参考文献：
  名称：

  Role of Y,C,Y-Chelating Ligands in Control Hydrolysis of Diorganotin Compounds

  摘要：

  The potential use of Y,C,Y-chelating ligands in control hydrolysis of diorganotin(IV) compounds of general formula L-1,L-2 SnPhX2 (L-1 = 2,6-(Me2NCH2)(2)C6H3, L-2 = 2,6-(MeOCH2)(2)C6H3, and X = Cl, CF3SO3, and [1-CB11H12]) is reported. The hydrolysis of moisture-sensitive compounds (LSnPh)-Sn-1(OTf)(2) (3) and L-2 SnPh(OTf)(2) (4) gave organotin(IV) cations {[(LSnPh)-Sn-1(OH2)(OTf)](+)[OTf](-)} (5) and {[L-2 SnPh(OH2)(OTf)](+)[OTf](-1) (6). Reported is also the preparation of diorganotin(IV) cations [(LSnPhCl)-Sn-1](+) [1-CB11H12]-} (7) and ( [(LSnPhCl)-Sn-2](+)[1-CB11H12](-)} (8) and the isolation of [PhL2 Sn-mu-(OH)(2)-SnL2 Ph](2+) 2*[1-CB11H12](-) (9), the final hydrolytic product of 8. The products were characterized by H-1, B-11, C-13, and Sn-119 NMR and IR spectroscopy, ESI/MS, and elemental analyses, and the structures of compounds 3 and 6 were determined by X-ray diffraction studies.

  DOI：

  10.1021/om8002015
• 作为产物：
  描述：

  [2,6-(Me2NCH2)2C6H3](Ph)SnCl2 、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以95%的产率得到benzene;1-[3-[(dimethylamino)methyl]benzene-2-id-1-yl]-N,N-dimethylmethanamine;tin(4+);trifluoromethanesulfonate
  参考文献：
  名称：

  Role of Y,C,Y-Chelating Ligands in Control Hydrolysis of Diorganotin Compounds

  摘要：

  The potential use of Y,C,Y-chelating ligands in control hydrolysis of diorganotin(IV) compounds of general formula L-1,L-2 SnPhX2 (L-1 = 2,6-(Me2NCH2)(2)C6H3, L-2 = 2,6-(MeOCH2)(2)C6H3, and X = Cl, CF3SO3, and [1-CB11H12]) is reported. The hydrolysis of moisture-sensitive compounds (LSnPh)-Sn-1(OTf)(2) (3) and L-2 SnPh(OTf)(2) (4) gave organotin(IV) cations {[(LSnPh)-Sn-1(OH2)(OTf)](+)[OTf](-)} (5) and {[L-2 SnPh(OH2)(OTf)](+)[OTf](-1) (6). Reported is also the preparation of diorganotin(IV) cations [(LSnPhCl)-Sn-1](+) [1-CB11H12]-} (7) and ( [(LSnPhCl)-Sn-2](+)[1-CB11H12](-)} (8) and the isolation of [PhL2 Sn-mu-(OH)(2)-SnL2 Ph](2+) 2*[1-CB11H12](-) (9), the final hydrolytic product of 8. The products were characterized by H-1, B-11, C-13, and Sn-119 NMR and IR spectroscopy, ESI/MS, and elemental analyses, and the structures of compounds 3 and 6 were determined by X-ray diffraction studies.

  DOI：

  10.1021/om8002015