2-[3-(pyridylamino)phenylazo]pyridine | 877458-82-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[3-(pyridylamino)phenylazo]pyridine
• 英文别名: 2-[2-(3-pyridylamino)phenylazo]pyridine；N-[2-(pyridin-2-yldiazenyl)phenyl]pyridin-3-amine
• CAS: 877458-82-7
• 化学式: C₁₆H₁₃N₅
• 分子量: 275.313
• InChiKey: YBRGSGKIMSFTLE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  62.5
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-[3-(pyridylamino)phenylazo]pyridine 在 triethylamine 、 N₂H₄ 作用下， 以 甲醇 为溶剂， 生成 [Co(II)(2-[3-(pyridylamino)phenylazo]pyridine(-H))2]
  参考文献：
  名称：

  Banerjee, Priyabrata; Peng, Shie-Ming; Lee, Gene Hsiatig, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2009, vol. 48, # 1, p. 25 - 29

  摘要：

  DOI：
• 作为产物：
  描述：

  ammonium polysulfide 、 [Co(II)(2-[3-(pyridylamino)phenylazo]pyridine(-H))2] 以 not given 为溶剂， 生成 cobalt(II) sulfide 、 2-[3-(pyridylamino)phenylazo]pyridine
  参考文献：
  名称：

  Banerjee, Priyabrata; Peng, Shie-Ming; Lee, Gene Hsiatig, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2009, vol. 48, # 1, p. 25 - 29

  摘要：

  DOI：

文献信息

• Mononuclear to Polynuclear Transition Induced by Ligand Coordination:  Synthesis, X-ray Structure, and Properties of Mono-, Di-, and Polynuclear Copper(II) Complexes of Pyridyl-Containing Azo Ligands
  作者：Srijit Das、Priyabrata Banerjee、Shie-Ming Peng、Gene-Hsiang Lee、Jinkwon Kim、Sreebrata Goswami

  DOI：10.1021/ic051029c

  日期：2006.1.1

  of two hydrated cupric salts (CuCl(2).2H(2)O and Cu(ClO(4))(2).6H(2)O) with three azopyridyl ligands, viz. 2-[(arylamino)phenylazo]pyridine [aryl = phenyl (HL(1a)), p-tolyl (HL(1b)), and 2-thiomethyl phenyl (HL(1c))], 2-[2-(pyridylamino)phenylazo]pyridine (HL(2)), and 2-[3-(pyridylamino)phenylazo]pyridine (HL(3)), afford the mononuclear [CuClL(1)] (1), dinuclear [Cu(2)X(2)L(2)(2)](n)()(+) (X = Cl,

  两种水合铜盐（CuCl（2）.2H（2）O和Cu（ClO（4））（2）.6H（2）O）与三个偶氮吡啶基配体的反应，即。2-[（（芳基氨基）苯基偶氮]吡啶[芳基=苯基（HL（1a）），对甲苯基（HL（1b））和2-硫甲基苯基（HL（1c））]，2- [2-（吡啶基氨基）苯基偶氮]吡啶（HL（2））和2- [3-（吡啶基氨基）苯基偶氮]吡啶（HL（3）），得到单核[CuClL（1）]（1），双核[Cu（2）X （2）L（2）（2）]（n）（）（+）（X = Cl，H（2）O，ClO（4）; n = 0，1; 2，3）和多核[CuClL （3）]（n）（）（4）分别以高收率配合。报告了这些配合物1-4的代表性X射线结构。对4的X射线结构分析显示出无限的一维锯齿形链，采用锯齿状结构。在配合物2-4上进行的可变温度低温磁测量（2-300 K）显示，J值为-1的铜中心之间的磁相互作用较弱。04、9.88和-1
• Isolation and Characterization of Zn ^II and Hg ^II Coordination Polymers with a Designed Azo‐Aromatic Ligand: Identification of Micrometer‐ and Nanometer‐Sized Particles
  作者：Priyabrata Banerjee、Soumitra Kar、Asim Bhaumik、Gene‐Hsiang Lee、Shie‐Ming Peng、Sreebrata Goswami

  DOI：10.1002/ejic.200600878

  日期：2007.2

  AbstractControlled layering of the deprotonated methanolic solution of the azo‐aromatic ligand [L3]– (HL3 = 2‐[3‐(pyridylamino)phenylazo]pyridine) over the aqueous/methanolic solutions of metal chlorides MCl2 (M = Zn, Hg) afforded nano‐ and micrometer‐sized particles of the metal–organic polymeric complexes of [HgCl(C16H12N5)]∞ (1) and [ZnCl(C16H18N5O3)]∞ (2). Time‐dependent growth of the above particles is followed by the SEM and TEM analyses of the samples at different time intervals. The X‐ray structure of the mercury polymer reveals that two infinite 1D, zigzag chains composed of [HgCl(L3)]∞ units run along the a axis antiparalelly. The polynuclear Zn compound, in contrast, agglomerates fast to form hemispherical microcrystals with a diamondoid surface morphology, and no suitable X‐ray quality crystal of this complex could be isolated. Powder XRD analyses of the samples as well as thermogravimetric analysis (TGA) are used for their characterization. Unusually, these metal–organic polymers of the reference d10 metal ions are green and absorb in the low‐energy region of the visible spectrum, 660–675 nm. Semiempirical calculations on a representative complex 1 suggest that the transitions in the complexes involve ligand orbitals. These also show multiple emissions in the blue‐green region. The Zn complex, which is microporous, shows reversible adsorption/desorption of N2 and H2 gasses. The mercury polymer, on the other hand, shows poor adsorption ability. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)