| 54348-75-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 54348-75-3
• 化学式: C₆₄H₇₂Fe₂N₈O
• 分子量: 1081.02
• InChiKey: RQCGGVBAYFKBIR-OIYSXBEXSA-N

反应信息

• 作为反应物：
  描述：

  、 silver perchlorate 在 I₂ 作用下， 以 二氯甲烷 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Electrochemical synthesis and characterization of the single-electron oxidation products of ferric porphyrins

  摘要：

  DOI：

  10.1021/ja00386a031
• 作为产物：
  描述：

  iron(II) bromide 、 ethioporphyrin I 在 2,6-二甲基吡啶 、 aluminum oxide 、 air 作用下， 以 not given 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  A Phototriggered Molecular Spring for Aerobic Catalytic Oxidation Reactions

  摘要：

  The first catalytic oxidation reactions with cofacial bisporphyrins using molecular oxygen as the terminal oxidant are presented. The photocatalytic reactions proceed under mild conditions (ambient temperature and pressure) without the need for a co-reductant. A systematic reactivity study of the photooxidation of dimethyl sulfide (DMS) with a homologous series of bisiron(III) mu-oxo porphyrins containing dibenzofuran, xanthene, or no bridge reveals that the facility of these processes is markedly dependent on the vertical flexibility of the catalyst to provide a phototriggered molecular spring.

  DOI：

  10.1021/ja026017u

文献信息

• Isolable Iron(II)–Porphycene Derivative Stabilized by Introduction of Trifluoromethyl Groups on the Ligand Framework
  作者：Kazuyuki Ito、Takashi Matsuo、Isao Aritome、Yoshio Hisaeda、Takashi Hayashi

  DOI：10.1246/bcsj.81.76

  日期：2008.1.15

  Two iron porphycene complexes having four trifluoromethyl groups, chloro-2,7,12,17-tetraethyl-3,6,13,16-tetrakis(trifluoromethyl)porphycenatoiron(III) [FeIIIClEtio(CF3)4Pc] and its μ-oxo dimer [Fe...

  具有四个三氟甲基的两个铁卟啉络合物，氯-2,7,12,17-四乙基-3,6,13,16-四(三氟甲基)卟啉铁(III)[FeIIIClEtio(CF3)4Pc]及其μ-氧代二聚体[铁...