(bis[2-(3,5-dimethyl-1-pyrazolyl)ethyl]amine)(dicyanamide)copper(II) perchlorate | 1379459-69-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: (bis[2-(3,5-dimethyl-1-pyrazolyl)ethyl]amine)(dicyanamide)copper(II) perchlorate
• CAS: 1379459-69-4
• 化学式: C₂N₃*C₁₄H₂₃N₅*ClO₄*Cu
• 分子量: 490.409
• InChiKey: MTBFKICBNUFCRN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) perchlorate hexahydrate 、 sodium dicyanamide 、 bis[2-(3,5-dimethyl-1H-pyrazol-1-yl)ethyl]amine 以 水 为溶剂， 以75%的产率得到(bis[2-(3,5-dimethyl-1-pyrazolyl)ethyl]amine)(dicyanamide)copper(II) perchlorate
  参考文献：
  名称：

  Dicyanamido-metal(II) complexes. Part 6: 1D polymeric copper(II) complexes bridging by dicyanamide. Effect of copper(II) salt on the nature of the polymeric product

  摘要：

  The complexes {[Cu(L)(mu(1,5)-dca)](ClO4)}(n) (1, L = bepza; 2, L = bedmpza) and [Cu(L)(mu(1,5)-dca)(dca)](n) (3, L = bepza; 4, L = bedmpza), where dca = dicyanamide anion, bepza = bis[2-(1-pyrazolyl)ethyl)]amine and bedmpza = bis[2-(di-2,5-dimethyl-1-pyrazolyl)ethyl)]amine, were synthesized and characterized by spectroscopic techniques. The crystal structures of complexes 1 and 3 confirmed their polymeric 1D chain nature through the two terminal nitrile groups of the mu 1,5-bridging dicyanamido ligand. The magnetic susceptibility measurements of the two complexes 1 and 3 revealed the occurrence of very weak antiferromagnetic coupling with J values of -0.17 and -0.03 cm (1), respectively. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.03.009