Trimethylen-Biradikal | 32458-33-6

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 英文名称: Trimethylen-Biradikal
• 英文别名: Trimethylendiradikal；propane-1,3-diyl；1,3-propanediyl radical；propane
• CAS: 32458-33-6；92567-96-9
• 化学式: C₃H₆
• 分子量: 42.0806
• InChiKey: CUJPFPXNDSIBPG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Trimethylen-Biradikal 以32%的产率得到
  参考文献：
  名称：

  MOTYL, K. M.;NORTON, J. R.;SCHAUER, C. K.;ANDERSON, O. P., J. AMER. CHEM. SOC., 1982, 104, N 25, 7325-7327

  摘要：

  DOI：
• 作为产物：
  描述：

  丙烷 生成 三聚丙烯 、 dimethylcarbene 、 Trimethylen-Biradikal 、 Ethylcarben
  参考文献：
  名称：

  Site specificity in molecular hydrogen elimination from photodissociation of propane at 157 nm

  摘要：

  Site effects on the molecular hydrogen elimination from propane at 157 nm excitation have been studied using the photofragment translational spectroscopic technique. Experimental results indicate that H2 elimination from the internal carbon of propane (2,2-elimination) is predominant while eliminations from the terminal carbon (1,1- and 1,3-elimination) and the vicinal carbons (1,2-elimination) are minor. The translational energy distributions obtained for these processes also show that the dynamics of H2 eliminations from different sites are significantly different. Relative branching ratios of the atomic hydrogen (H) and the molecular hydrogen (H2) elimination processes were also determined.

  DOI：

  10.1063/1.479507

文献信息

• Site specificity in molecular hydrogen elimination from photodissociation of propane at 157 nm
  作者：S. M. Wu、J. J. Lin、Y. T. Lee、X. Yang

  DOI：10.1063/1.479507

  日期：1999.8

  Site effects on the molecular hydrogen elimination from propane at 157 nm excitation have been studied using the photofragment translational spectroscopic technique. Experimental results indicate that H2 elimination from the internal carbon of propane (2,2-elimination) is predominant while eliminations from the terminal carbon (1,1- and 1,3-elimination) and the vicinal carbons (1,2-elimination) are minor. The translational energy distributions obtained for these processes also show that the dynamics of H2 eliminations from different sites are significantly different. Relative branching ratios of the atomic hydrogen (H) and the molecular hydrogen (H2) elimination processes were also determined.
• MOTYL, K. M.;NORTON, J. R.;SCHAUER, C. K.;ANDERSON, O. P., J. AMER. CHEM. SOC., 1982, 104, N 25, 7325-7327
  作者：MOTYL, K. M.、NORTON, J. R.、SCHAUER, C. K.、ANDERSON, O. P.

  DOI：——

  日期：——