N-[2-(4-methoxyphenyltelluro)ethyl]piperidine | 1353012-52-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: N-[2-(4-methoxyphenyltelluro)ethyl]piperidine
• 英文别名: Piperidine, 1-[2-[(4-methoxyphenyl)telluro]ethyl]-；1-[2-(4-methoxyphenyl)tellanylethyl]piperidine
• CAS: 1353012-52-8
• 化学式: C₁₄H₂₁NOTe
• 分子量: 346.927
• InChiKey: QPFKNCRHWJSIPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.93
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  sodium tetrachloropalladate(II) 、 N-[2-(4-methoxyphenyltelluro)ethyl]piperidine 以 水 、 丙酮 为溶剂， 以80%的产率得到[PdCl₂(N-[2-(4-methoxyphenyltelluro)ethyl]piperidine)]
  参考文献：
  名称：

  Palladiumd(II) complexes of N-{2-(aryltelluro)ethyl}morpholine/piperidine: Synthesis, structure, application in Heck coupling and unprecedented conversion into nano-sized PdTe

  摘要：

  The complexes, [PdCl2(L)] (1-2) (L = N-{2-(aryltelluro)ethyl}morpholine/piperidine) have been synthesized and characterized by multi-nuclei NMR and single crystal X-ray crystallography. They on reaction with aryl chloride/bromide and morpholine/piperidine give similar to 5 nm size nano-particles of PdTe. The 0.005 mol% of 2 is suitable for Heck coupling (conversion up to 93%). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.10.015
• 作为产物：
  描述：

  1-(2-氯乙基)哌啶盐酸盐 、 bis(4-methoxyphenyl)ditelluride 以 乙醇 为溶剂， 生成 N-[2-(4-methoxyphenyltelluro)ethyl]piperidine
  参考文献：
  名称：

  Palladiumd(II) complexes of N-{2-(aryltelluro)ethyl}morpholine/piperidine: Synthesis, structure, application in Heck coupling and unprecedented conversion into nano-sized PdTe

  摘要：

  The complexes, [PdCl2(L)] (1-2) (L = N-{2-(aryltelluro)ethyl}morpholine/piperidine) have been synthesized and characterized by multi-nuclei NMR and single crystal X-ray crystallography. They on reaction with aryl chloride/bromide and morpholine/piperidine give similar to 5 nm size nano-particles of PdTe. The 0.005 mol% of 2 is suitable for Heck coupling (conversion up to 93%). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.10.015

文献信息

• Palladiumd(II) complexes of N-{2-(aryltelluro)ethyl}morpholine/piperidine: Synthesis, structure, application in Heck coupling and unprecedented conversion into nano-sized PdTe
  作者：Pradhumn Singh、Dipanwita Das、Arun Kumar、Ajai K. Singh

  DOI：10.1016/j.inoche.2011.10.015

  日期：2012.1

  The complexes, [PdCl2(L)] (1-2) (L = N-2-(aryltelluro)ethyl}morpholine/piperidine) have been synthesized and characterized by multi-nuclei NMR and single crystal X-ray crystallography. They on reaction with aryl chloride/bromide and morpholine/piperidine give similar to 5 nm size nano-particles of PdTe. The 0.005 mol% of 2 is suitable for Heck coupling (conversion up to 93%). (C) 2011 Elsevier B.V. All rights reserved.