1,5-diphenyl-3,7-dimethyl-2,4,6,8,9-pentaselena-3,7-disila-1,5-distannatricyclo[3.3.1.0(3,7)]nonane | 591772-15-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,5-diphenyl-3,7-dimethyl-2,4,6,8,9-pentaselena-3,7-disila-1,5-distannatricyclo[3.3.1.0(3,7)]nonane
• CAS: 591772-15-5
• 化学式: C₁₄H₁₆Se₅Si₂Sn₂
• 分子量: 872.672
• InChiKey: ZBIOBSYOQXNJII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.71
• 重原子数：
  23
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  selenium 、 1,2-二甲基-1,1,2,2-四氯二硅烷 、 苯基三氯化锡 、 三乙基硼氢化锂 以 四氢呋喃 为溶剂， 以47%的产率得到1,5-diphenyl-3,7-dimethyl-2,4,6,8,9-pentaselena-3,7-disila-1,5-distannatricyclo[3.3.1.0(3,7)]nonane
  参考文献：
  名称：

  Heteronoradamantanes Me2Si2(RM)2E5 (RM=MeGe, PhSn; E=S, Se)

  摘要：

  The reaction of a 1:2 molar mixture of 1,2-Me2Si2Cl4 and MeGeCl3 with H2S/NEt3 yielded Me2Si2(MeGe)(2)S-5 (1), the first mixed silicon-germanium chalcogenide with a noradamantane-like structure, while the treatment of a 1:2 mixture of 1,2-Me2Si2Cl4 and PhSnCl3 with Li2Se resulted in the formation of the first silicon- and tin-containing noradamantane Me2Si2(phSn)(2)Se-5 (2). Both compounds have been characterized by NMR spectroscopy (H-1, C-11, Si-29, Se-77 and Sn-119). The molecular structure of I in the solid state is reported. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00226-2

文献信息

• Heteronoradamantanes Me2Si2(RM)2E5 (RM=MeGe, PhSn; E=S, Se)
  作者：Uwe Herzog、Horst Borrmann

  DOI：10.1016/s0022-328x(03)00226-2

  日期：2003.5

  The reaction of a 1:2 molar mixture of 1,2-Me2Si2Cl4 and MeGeCl3 with H2S/NEt3 yielded Me2Si2(MeGe)(2)S-5 (1), the first mixed silicon-germanium chalcogenide with a noradamantane-like structure, while the treatment of a 1:2 mixture of 1,2-Me2Si2Cl4 and PhSnCl3 with Li2Se resulted in the formation of the first silicon- and tin-containing noradamantane Me2Si2(phSn)(2)Se-5 (2). Both compounds have been characterized by NMR spectroscopy (H-1, C-11, Si-29, Se-77 and Sn-119). The molecular structure of I in the solid state is reported. (C) 2003 Elsevier Science B.V. All rights reserved.