(乙腈)五羰基锰(I)四氟硼酸盐 | 75008-28-5

• 中文名称: (乙腈)五羰基锰(I)四氟硼酸盐
• 英文名称: (acetonitrile)pentacarbonylmanganese(I) tetrafluoroborate
• CAS: 75008-28-5
• 化学式: BF₄*C₇H₃MnNO₅
• 分子量: 322.847
• InChiKey: LSUWWUQPFZIKQJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (乙腈)五羰基锰(I)四氟硼酸盐 在 吡啶 、 硝基甲烷 作用下， 以 硝基甲烷 为溶剂， 生成 tricarbonyltripyridinemanganese(I) tetrafluoroborate
  参考文献：
  名称：

  Cis labilization of ligand dissociation. 7. Substitution reactions of acetonitrilepentacarbonylmanganese(I). Cis labilization via nucleophilic attack at metal-bound carbonyl

  摘要：

  DOI：

  10.1021/ja00539a008
• 作为产物：
  描述：

  羰基镁 在 Na/Hg 、 CH₃CN 作用下， 以 四氢呋喃 、 二氯甲烷 、 乙腈 为溶剂， 生成 (乙腈)五羰基锰(I)四氟硼酸盐
  参考文献：
  名称：

  Raab, Klaus; Nagel, Ulrich; Beck, Wolfgang, Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1983, vol. 38, # 11, p. 1466 - 1476

  摘要：

  DOI：

文献信息

• Highly reduced organometallics 52. Synthesis and chemistry of tricarbonylnitrosylmanganate(2−), [Mn(CO)3(NO)]2−
  作者：Yu-Sen Chen、John E. Ellis

  DOI：10.1016/s0020-1693(99)00546-0

  日期：2000.4

  dianion, isoelectronic with [Fe(CO)4]2− and [Mn(CO)4]3−. Reactions of [Mn(CO)3(NO)]2− with Ph3SnCl, Mn(CO)4(NO) and Fe(CO)5, followed by metathesis, provided the new derivatives [Et4N][Mn(CO)3(NO)(SnPh3)], [PPN]2[Mn2(CO)6(NO)2], and [PPN]2[MnFe(CO)7(NO)]. On the basis of IR spectral data the latter two have been formulated to contain non-bridged structures analogous to that previously established for the

  用过量的钠汞齐在20°C下于THF中处理Mn（CO）3（NO）（PPh 3），然后用穴盘2.2.2或两当量处理。的三仲丁基硼氢化钾提供了高分离度的空气敏感黄色固体（≥80％），被识别为[Na（crypt.2.2.2）] 2 [Mn（CO）3（NO）]和K 2 [Mn（ CO）3（NO）]。这些产物包含唯一已知的，与[Fe（CO）4 ] 2−和[Mn（CO）4 ] 3−等电子的混合羰基亚硝基金属化物二价阴离子。[Mn（CO）3（NO）] 2−与Ph 3的反应SnCl，Mn（CO）4（NO）和Fe（CO）5，然后进行复分解，提供了新的衍生物[Et 4 N] [Mn（CO）3（NO）（SnPh 3）]，[PPN] 2 [ Mn 2（CO）6（NO）2 ]和[PPN] 2 [MnFe（CO）7（NO）]。根据红外光谱数据，后两者已被配制为包含非桥接结构，该结构类似于先前为等电子盐[PPN] 2 [Fe
• Formation of metal-metal bonds by ion-pair annihilation. Dimanganese carbonyls from manganate(I-) anions and manganese(I) cations
  作者：K. Y. Lee、D. J. Kuchynka、J. K. Kochi

  DOI：10.1021/om00152a010

  日期：1987.9.1
• Reaction of [PPN][Re(CO)5] with [Mn(CO)5(C2H4)][BF4], a rapid two-electron, ethylene transfer reaction, PPN=bis(triphenylphosphine)nitrogen(1+)
  作者：David C. Hoth、Jim D. Atwood

  DOI：10.1016/s0020-1693(02)00793-4

  日期：2002.5

  Reaction of Re(CO)(5)(-) with Mn(CO)(5)(C2H4)(+) produces initially, among other products, Re(CO)(5)(C2H4)(+) and Mn(CO)(5)(-). The ethylene transfer accompanied by a two-electron process provides another example of rapid two-electron reactions, more rapid than single electron transfer. The ultimate products are bimetallic from single electron reactions. (C) 2002 Elsevier Science B.V. All rights reserved.
• Herberhold, Max; Ott, Jutta; Haumaier, Ludwig, Chemische Berichte, 1985, vol. 118, # 8, p. 3143 - 3150
  作者：Herberhold, Max、Ott, Jutta、Haumaier, Ludwig

  DOI：——

  日期：——
• Cationic carbonylmanganese complexes of the olefinic ligand tri(1-cyclohepta-2,4,6-trienyl)phosphane, P(C7H7)3
  作者：Max Herberhold、Andreas Pfeifer、Wolfgang Milius

  DOI：10.1016/j.jorganchem.2003.07.012

  日期：2003.11

  A series of tetrafluoroborate salts of carbonylmanganese cations was obtained which contain the olefinic phosphane, P(C7H7)3 (1). Whereas 1 is a conventional two-electron phosphatic ligand ([P]) in Mn(CO)(5)[P]}BF4 (2)-as in the neutral bromide or trifluoroacetate complexes, cis-Mn(X)(CO)(4)[P]}BF4 (X = Br (4b), CF3COO (4d)) and mer, trans-Mn(X)(CO)(3)[P]}BF4 (X = Br (5b), CF3COO (5d))-it is transformed into a four-electron chelate ligand ([P']) if 4b and 5b react with AgBF4 to give cis-Mn(CO)(4)[P']}BF4 (7) and mer, trans- Mn(CO)(3)[P][P']}BF4 (8), respectively, ([P'] = P(C7H7)(2)(eta(2)-C7H7)). An analogous halide abstraction by AgBF4 converts mer-Mn(I)(CO)(3)[P']} (6c) into fac-Mn(CO)(3)[P"]}BF4 (9) which contains the phosphane as a six-electron ligand ([P"]) with an eta(4)-norcaradienyl ring ([P"] = P(C7H7)(2)(eta(4)-C7H7)). The coordinated eta(2)-cyclohepta-2,4,6-trienyl substituent in 7 and 8 is displaced by tert-butyl isocyanide (L) to give cis-Mn(CO)(4)[P](L)}BF4 (10) and mer,trans-Mn(CO)(3)[P](2)(L)}BF4 (11), respectively. The structures of the new cations have been assigned on the basis of their carbonyl stretching absorption patterns in the IR spectra and by their H-1-, C-13- and P-31-NMR spectra. Single-crystal X-ray structure analyses were carried out for 7 and 9. (C) 2003 Elsevier B.V. All rights reserved.