3-phenylthio-phtalic acid | 68621-19-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 3-phenylthio-phtalic acid
• 英文别名: 3-(phenylthio)-phthalic acid；3-(Phenylthio)phthalic acid；3-phenylsulfanylphthalic acid
• CAS: 68621-19-2
• 化学式: C₁₄H₁₀O₄S
• 分子量: 274.297
• InChiKey: ZCZMVVHJHQXENA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  99.9
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3-phenylthio-phtalic acid 在 aluminum (III) chloride 、 偶氮二甲酸二异丙酯 、 乙酸酐 、 三苯基膦 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 58.0h， 生成 9-oxo-9H-thioxanthen-1-carboxylic acid-(2-acryloyloxyethyl ester)
  参考文献：
  名称：

  Radiation curable compositions

  摘要：

  根据公式(I)的可聚合的Norrish II型光引发剂：含有公式(I)的可聚合Norrish II型光引发剂的辐射固化组合物和喷墨墨水表现出与辐射固化组合物和喷墨墨水的更好兼容性和溶解性，并且在固化后显示出光引发剂及其残留物的可萃取量较低。

  公开号：

  US08536217B2
• 作为产物：
  描述：

  4-硝基-2-苯基异吲哚-1,3-二酮 在 溶剂黄146 、 sodium hydroxide 作用下， 以 水 、 二甲基亚砜 为溶剂， 反应 2.0h， 生成 3-phenylthio-phtalic acid
  参考文献：
  名称：

  Radiation curable compositions

  摘要：

  根据公式(I)的可聚合的Norrish II型光引发剂：含有公式(I)的可聚合Norrish II型光引发剂的辐射固化组合物和喷墨墨水表现出与辐射固化组合物和喷墨墨水的更好兼容性和溶解性，并且在固化后显示出光引发剂及其残留物的可萃取量较低。

  公开号：

  US08536217B2

文献信息

• RADIATION CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110159203A1

  公开（公告）日：2011-06-30

  A polymerizable Norrish Type II photoinitiator according to Formula (I): . Radiation curable compositions and inkjet inks containing the polymerizable Norrish Type II photoinitiator of Formula (I) exhibit improved compatibility with and solubility in radiation curable compositions and inkjet inks, and exhibit low extractable amounts of the photoinitiator and its residues after curing.

  根据公式（I）的聚合性诺里希II型光引发剂： . 含有公式（I）的聚合性诺里希II型光引发剂的辐射固化组合物和喷墨油墨在辐射固化组合物和喷墨油墨中表现出优异的相容性和溶解性，并且在固化后光引发剂及其残留物的可提取量较低。
• [EN] POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS<br/>[FR] PHOTOINITIATEURS POLYMÉRISABLES ET COMPOSITIONS DURCISSABLES PAR RAYONNEMENTS
  申请人：AGFA GRAPHICS NV

  公开号：WO2010029017A1

  公开（公告）日：2010-03-18

  A new type of polymerizable Norrish Type II photoinitiators having an optionally substituted benzophenone group or an optionally substituted thioxanthone group is disclosed exhibiting improved compatibility with and solubility in radiation curable compositions. Radiation curable compositions and inkjet inks containing these polymerizable Norrish Type Il photoinitiators, exhibiting low extractable amounts of the photoinitiators and their residues after curing, are also disclosed.

  本文披露了一种新型可聚合的Norris Type II光引发剂，其具有可选取代的苯基酮基团或可选取代的噻吩酮基团，表现出与辐射固化组合物的改进兼容性和溶解性。同时还披露了含有这些可聚合Norris Type II光引发剂的辐射固化组合物和喷墨墨水，这些光引发剂及其残留物在固化后的萃取量较低。
• Acid halide and/or acyllactam functional compounds and polylactam block copolymers derived therefrom
  申请人：STAMICARBON B.V.

  公开号：EP0404255A1

  公开（公告）日：1990-12-27

  The invention relates to acid halide and/or acyllactam functional compounds, to polylactam block copolymers derived therefrom by lactam polymerization at a lactam group, and to the use of such block copolymers in polyamide mixtures. The compounds contain liquid crystalline compounds or compounds which combine with acyllactam to form a compound with liquid crystalline properties. The products of this invention are useful as accelerators in the preparation of nylon block copolymers, in particular block copolymers with improved stiffness. The block copolymers are useful in products requiring good tensile strength, chemical resistance and/or heat resistance, and are particularly useful in electrical engineering applications and in the aircraft industry.

  该发明涉及酸卤和/或酰乳酰胺功能化合物，以及由此类化合物通过在乳酰胺基团上进行乳酰聚合而衍生的聚乳酰块共聚物，以及在聚酰胺混合物中使用这种块共聚物。这些化合物含有液晶化合物或与酰乳酰胺结合形成具有液晶性能的化合物。该发明的产品可用作尼龙块共聚物制备中的催化剂，特别是改善了刚度的块共聚物。这些块共聚物适用于需要良好抗拉强度、化学抵抗力和/或耐热性的产品，尤其适用于电气工程应用和航空工业中。
• POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110195198A1

  公开（公告）日：2011-08-11

  A polymerizable Norrish Type II photoinitiators includes an optionally substituted benzophenone group or an optionally substituted thioxanthone group exhibiting improved compatibility with and solubility in radiation curable compositions. Radiation curable compositions and inkjet inks can contain these polymerizable Norrish Type II photoinitiators, exhibiting low extractable amounts of the photoinitiators and their residues after curing.

  一种可聚合的Norrish二型光引发剂，包括一个可选取的取代苯基酮基团或一个可选取的取代噻吩酮基团，表现出与辐射可固化组合物的良好相容性和溶解性。这些可聚合的Norrish二型光引发剂可用于辐射可固化组合物和喷墨油墨中，固化后其光引发剂和残留物的可提取量较低。
• Heat activatable adhesive for wire scribed circuits
  申请人：Advanced Interconnection Technology, Inc.

  公开号：EP0212238A2

  公开（公告）日：1987-03-04

  A non-blocking, solid, adhesive composition which can be activated upon application of sufficient heat or ultra­sonic energy without becoming C-staged, comprising (a) a first component having an epoxide-, hydroxy- or unsaturated functionality grater than 2, said polymeric resin being selected from the group consisting of polyesters, poly­urethanes and epoxies; (b) a second component comprised of at least one filler, or at least one polyfunctional compound containing a polyaromatic backbone and having an average molecular weight below about 7000, or mixtures thereof, the weight ratio of said first component so said second com­ponent being between about 1.5 : 1 and about 9 : 1; and (c) a curing agent which is capable of reacting or initi­ating a reactio n with the functional groups of the poly­meric resin to form crosslinks and cure the polymeric resin to a C-stage upon application of sufficient energy in the form of heat or radiant energy, said curing agent being non-reactive or blocked at the condition which will acti­vate the adhesive composition, said curing agent being pre­sent in an amount sufficient to C-stage the polymeric resin. The adhesive composition is flexible, and in the C-stage, is capable of forming an infusible composition which does not melt, flow or decompose when exposed for 10 seconds to molten solder at 260°C and does not soften when exposed for 1 minute to dichloromethane at 25°C. The adhesive composi­tion is suitable for bonding wire to a surface, to another wire or to itself.

  一种非阻塞性固体粘合剂组合物，可在施加足够的热量或超声波能量时被激活，而不会变成 C 型，包括 (a) 第一组份，其环氧化、羟基或不饱和官能度大于 2，所述聚合物树脂选自聚酯、聚氨酯和环氧树脂组成的组；(b) 由至少一种填料或至少一种含有多芳香族骨架且平均分子量低于约 7000 的多官能团化合物或其混合物组成的第二组分，所述第一组分与所述第二组分的重量比在约 1.5 : 1至约9 : 1之间；以及 (c) 一种固化剂，能够与聚合树脂的官能团反应或引发反应，以形成交联，并在施加足够的热能或辐射能形式的能量时将聚合树脂固化至C阶段，所述固化剂在将激活粘合剂组合物的条件下不发生反应或被阻断，所述固化剂的存在量足以使聚合树脂C阶段。该粘合剂组合物具有柔韧性，在 C 阶段能够形成一种可注入的组合物，该组合物在 260°C 的温度下与熔融焊料接触 10 秒钟不会熔化、流动或分解，在 25°C 的温度下与二氯甲烷接触 1 分钟不会软化。这种粘合剂组合物适用于将导线粘合到表面、另一根导线或导线本身。