sodium 2-(diethoxyphosphoryl)indane-1-carboxylate | 1009443-09-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: sodium 2-(diethoxyphosphoryl)indane-1-carboxylate
• 英文别名: sodium;2-diethoxyphosphoryl-2,3-dihydro-1H-indene-1-carboxylate
• CAS: 1009443-09-7
• 化学式: C₁₄H₁₈O₅P*Na
• 分子量: 320.257
• InChiKey: XHKYRMLJZSYGCL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.29
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  75.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  1H-茚-3-羧酸 在 sodium methylate 、 亚磷酸二乙酯 、 zinc(II) chloride 作用下， 以 甲醇 、 乙醚 为溶剂， 反应 1.0h， 生成 sodium 2-(diethoxyphosphoryl)indane-1-carboxylate
  参考文献：
  名称：

  具有茚满-1-羧酸部分的新型功能化有机磷酸及其衍生物的合成

  摘要：

  AbstractThe addition of trimethylsilyl esters of trivalent phosphorus acids to trimethylsilyl ester of 1 H‐indene‐3‐carboxylic acid has been studied. The convenient syntheses of new functionalized organophosphorus acids and their derivatives with indan‐1‐carboxylic acid moieties have been proposed. Water‐soluble sodium salts of the corresponding acids were also obtained.

  DOI：

  10.1002/hc.21400

文献信息

• Synthesis of new organophosphorus-substituted derivatives of functionalized propionates and their analogues
  作者：Andrey A. Prishchenko、Mikhail V. Livantsov、Olga P. Novikova、Ludmila I. Livantsova、Valery S. Petrosyan

  DOI：10.1002/hc.20446

  日期：2008.5

  trivalent organophosphorus acids to various functionalized acrylates and their cyclic analogues is proposed as convenient methods for the synthesis of new 2-trimethylsiloxycarbonyl-substituted alkylphosphonites and their derivatives under mild conditions. Also the new functionalized derivatives of these phosphonites, including amino, amido, and amino acids fragments as well as certain properties of these

  三价有机磷酸的三甲基甲硅烷基酯与各种官能化丙烯酸酯及其环状类似物的亲核或自由基加成被提议作为在温和条件下合成新的 2-三甲基甲硅烷氧基羰基取代的烷基亚膦酸酯及其衍生物的便捷方法。此外，这些亚膦酸酯的新官能化衍生物，包括氨基、酰胺基和氨基酸片段以及这些化合物的某些性质，作为官能化丙酸酯及其类似物的新型有机磷取代衍生物的重要前体。© 2008 Wiley Periodicals, Inc. 杂原子化学 19:418–428, 2008; 在线发表于 Wiley InterScience (www.interscience.wiley.com)。DOI 10.1002/hc.20446
• Synthesis of new functionalized organophosphorus acids and their derivatives with indan-1-carboxylic acid moieties
  作者：Andrey A. Prishchenko、Mikhail V. Livantsov、Olga P. Novikova、Ludmila I. Livantsova、Valery S. Petrosyan

  DOI：10.1002/hc.21400

  日期：2017.9

  AbstractThe addition of trimethylsilyl esters of trivalent phosphorus acids to trimethylsilyl ester of 1 H‐indene‐3‐carboxylic acid has been studied. The convenient syntheses of new functionalized organophosphorus acids and their derivatives with indan‐1‐carboxylic acid moieties have been proposed. Water‐soluble sodium salts of the corresponding acids were also obtained.