(E)-octyl 3-(2,5-dimethoxy-2,5-dihydrofuran-2-yl)acrylate | 1334168-06-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E)-octyl 3-(2,5-dimethoxy-2,5-dihydrofuran-2-yl)acrylate
• 英文别名: octyl (E)-3-(2,5-dimethoxy-2H-furan-5-yl)prop-2-enoate
• CAS: 1334168-06-7
• 化学式: C₁₇H₂₈O₅
• 分子量: 312.406
• InChiKey: HHSAAMZGVLOKMC-ZRDIBKRKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  22
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  甲醇 、 (E)-octyl-3-(furan-2-yl)acrylate 在 lithium perchlorate 作用下， 以 环己烷 为溶剂， 以96%的产率得到(E)-octyl 3-(2,5-dimethoxy-2,5-dihydrofuran-2-yl)acrylate
  参考文献：
  名称：

  Heterogeneous continuous flow synthetic system using cyclohexane-based multiphase electrolyte solutions

  摘要：

  The discovery that supporting electrolytes can be effectively confined in typical organic solvents in a c-Hex-based multiphase electrolyte solution has led to the development of a novel heterogeneous continuous flow synthetic system. PTFE fiber functions as a separation filter that can efficiently isolate the c-Hex phase from multiphase electrolyte solutions. This system has demonstrated both electrochemical solvating and carbon-carbon bond forming reactions. Hydrophobic substrates can be introduced into the reactor as c-Hex solutions, which are then electrochemically transformed into the target hydrophobic products that pass through the PTFE fiber as c-Hex solutions. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.07.007

文献信息

• Heterogeneous continuous flow synthetic system using cyclohexane-based multiphase electrolyte solutions
  作者：Yohei Okada、Tomohiko Yoshioka、Mikio Koike、Kazuhiro Chiba

  DOI：10.1016/j.tetlet.2011.07.007

  日期：2011.9

  The discovery that supporting electrolytes can be effectively confined in typical organic solvents in a c-Hex-based multiphase electrolyte solution has led to the development of a novel heterogeneous continuous flow synthetic system. PTFE fiber functions as a separation filter that can efficiently isolate the c-Hex phase from multiphase electrolyte solutions. This system has demonstrated both electrochemical solvating and carbon-carbon bond forming reactions. Hydrophobic substrates can be introduced into the reactor as c-Hex solutions, which are then electrochemically transformed into the target hydrophobic products that pass through the PTFE fiber as c-Hex solutions. (C) 2011 Elsevier Ltd. All rights reserved.