(Z)-5-tetradecenal | 63851-42-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (Z)-5-tetradecenal
• 英文别名: (Z)-tetradec-5-enal
• CAS: 63851-42-3
• 化学式: C₁₄H₂₆O
• 分子量: 210.36
• InChiKey: HJCIVWWOKIXNOJ-KTKRTIGZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (Z)-5-tetradecenal 在 吡啶 、 lithium aluminium tetrahydride 作用下， 以 乙醚 、 苯 为溶剂， 生成 (Z)-5-十四碳烯-1-醇乙酸酯
  参考文献：
  名称：

  Kovalev, B. G.; Dzhumakulov, T.; Abduvakhabov, A. A., Doklady Chemistry, 1987, vol. 297, # 12, p. 544 - 548

  摘要：

  DOI：
• 作为产物：
  描述：

  5,5-二乙氧基戊醛 在 盐酸 、 sodium hexamethyldisilazane 作用下， 以 水 、 丙酮 为溶剂， 反应 13.5h， 生成 (Z)-5-tetradecenal
  参考文献：
  名称：

  Kovalev, B. G.; Dzhumakulov, T.; Abduvakhabov, A. A., Doklady Chemistry, 1987, vol. 297, # 12, p. 544 - 548

  摘要：

  DOI：

文献信息

• AGRICULTURAL PHEROMONE COMPOSITIONS COMPRISING POSITIONAL ISOMERS
  申请人：PROVIVI, INC.

  公开号：US20170135343A1

  公开（公告）日：2017-05-18

  The present disclosure provides pheromone compositions. In some aspects, the compositions taught herein comprise a pheromone chemically corresponding to the pheromone naturally produced by a given insect, along with at least one positional isomer of said pheromone. In various aspects, pheromone compositions of the present disclosure are able to modulate the response of the insect based on the ratio of natural pheromone to its positional isomer.

  本公开提供信息素组合物。在某些方面，本文所教授的组合物包括一种与某种昆虫自然产生的信息素在化学上相对应的信息素，以及至少一种该信息素的位置异构体。在各个方面，本公开的信息素组合物能够通过自然信息素与其位置异构体的比例来调节昆虫的反应。
• Tergal Gland Secretion of the Rove Beetle <i>Aleochara pseudochrysorrhoa</i> (Staphylinidae: Aleocharinae): Chemical Composition and Biological Roles
  作者：Maycon R. Silva、Diogo M. Vidal、Leonardo Figueiredo、Pamela T. Bandeira、Jan Bergmann、Paulo H. G. Zarbin

  DOI：10.1002/cbdv.202000483

  日期：2020.10

  Aleochara pseudochrysorrhoa has a glandular complex known as the tergal gland. Generally, the tergal gland secretion (TGS) has been described to have defensive function, but some reports point to a possible secondary function of this complex. For example, the TGS of the related species A. curtula has been demonstrated to possess an important role in intraspecies communication. In this work, we describe

  Aleochara pseudochrysorrhoa 有一个腺体复合体，称为 tergal 腺。通常，tergal 腺分泌物 (TGS) 已被描述为具有防御功能，但一些报告指出该复合体可能具有次要功能。例如，相关物种 A. curtula 的 TGS 已被证明在种内交流中具有重要作用。在这项工作中，我们描述了 A. pseudochrysorrhoa 男性和女性的 TGS 的化学成分。根据 GC/MS 和 GC-FT-IR 分析、保留指数和衍生产物鉴定了 11 种化合物。此外，还提供了关于 TGS 在交配行为中的生物学功能的简要研究，其中证明雌性 TGS 对雄性抓握反应的刺激依赖于浓度。
• Venom Alkaloid Chemistry of Australian Species of the<i>Monomorium rothsteini</i>Complex, with Particular Reference to Taxonomic Implications
  作者：Tappey H. Jones、Alan N. Andersen、Joshua C. Kenny

  DOI：10.1002/cbdv.200900005

  日期：2009.7

  carinatum complex were examined. Thirteen previously described trans‐2,5‐dialkylpyrrolidines were detected in these ants, along with the novel trans‐2‐ethyl‐5‐[(Z)‐tridec‐4‐enyl]pyrrolidine (6), whose structure was confirmed by synthesis. The extent of variation and the correlation observed in the morphology and venom chemistry in M. rothsteini samples is very strongly indicative of multiple species

  对澳大利亚 Monomorium rothsteini 复合物的形态和毒液生物碱进行了比较。这些蚂蚁是在澳大利亚从新南威尔士州西部、昆士兰州北部和北领地北部收集的。此外，还检查了来自 M. sordidum 复合体和 M. carinatum 复合体的样品。在这些蚂蚁中检测到 13 种先前描述的反式-2,5-二烷基吡咯烷，以及新型反式-2-乙基-5-[(Z)-tridec-4-enyl]吡咯烷 (6)，其结构已通过合成证实. 在 M. rothsteini 样本的形态和毒液化学中观察到的变异程度和相关性非常强烈地表明该复合体中有多个物种。
• ——
  作者：J. STEVEN McELFRESH、JOCELYN G. MILLAR、DANIEL RUBINOFF

  DOI：10.1023/a:1010310204552

  日期：——

  The Iepidopteran genus Saturnia has three representatives in North America, S. walterorum, S.mendocino, and S. albofasciata. (E4,Z9)-Tetradecadienal (E4,Z9-14 : Ald) was identified as a sex pheromone component for all three species by combinations of coupled gas chromatography-electroantennogram detection (GC-EAD), GC-mass spectrometry (MS), and field trials. In field trials, all three species were strongly attracted to (E4,Z9-14 : Ald) as a single component. Small amounts of (Z)-9-tetradecenal (Z9-14: Ald) also were found in extracts of all three species, but blends of this compound with E4,Z9-14 : Aid were no more attractive to male moths than E4,Z9-14 : Aid alone. Extracts of pheromone glands of female S. walterorum occasionally contained a third, trace compound eliciting responses from male antennae in GC-EAD experiments, but this compound was not identified. It is suggested that the three species can use the same, single component as a sex attractant because the flight period of S. albofasciata (Fall) is different than that of the other two species (spring), whereas the geographic distributions of S. mendocino and S. walterorum overlap over only small portions of their ranges. Furthermore, the latter two species readily hybridize, so there may be minimal fitness cost to cross-attraction.
• KOVALEV, B. G.;DZHUMAKULOV, T.;ABDUVAXABOV, A. A.;SADYKOV, A. S., DOKL. AN CCCP, 297,(1987) N 6, 1381-1386
  作者：KOVALEV, B. G.、DZHUMAKULOV, T.、ABDUVAXABOV, A. A.、SADYKOV, A. S.

  DOI：——

  日期：——