(triphenylphosphine)2Ag(4-carbazol-9-yl-benzoic acid-H) | 937269-48-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: (triphenylphosphine)2Ag(4-carbazol-9-yl-benzoic acid-H)
• 英文别名: (PPh3)2Ag(4-carbazol-9-yl-benzoic acid-H)
• CAS: 937269-48-2
• 化学式: C₅₅H₄₂AgNO₂P₂
• 分子量: 918.76
• InChiKey: WJQRALAJBCAQMG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-(9H-carbazol-9-yl)benzoic acid 在 NaOH 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 (triphenylphosphine)2Ag(4-carbazol-9-yl-benzoic acid-H)
  参考文献：
  名称：

  Synthesis, photoluminescence and electrochemical properties of a series of carbazole-functionalized ligands and their silver(I) complexes

  摘要：

  A series of carbazole-functionalized carboxylate ligands (N-carbazolylacetic acid (L1), 4-carbazol-9-yl-benzoic acid (L2), and 3-(4-carbazol-9-yl-phenyl) -acrylic acid (L3)) and their corresponding silver complexes were designed and synthesized and the structures were determined by single crystal X-ray diffractions. The silver atoms in the complexes are in tetrahedral geometry coordinated with two oxygen from carboxylic and two phosphorous atoms from triphenylphosphine. The complexes exhibit excellent electrochemical characters in solution and strong photoluminescence in the solid state. The emission wavelengths of the compounds can be tuned (from ultraviolet to visible region) by introducing of the second coordinating ligand Iriphenylphosphine and by elongation of the conjugation moieties. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.10.043