chloroglycyl-DL-methioninatopalladium(II) monohydrate | 141624-93-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: chloroglycyl-DL-methioninatopalladium(II) monohydrate
• CAS: 141624-93-3
• 化学式: C₇H₁₃ClN₂O₃PdS*H₂O
• 分子量: 365.146
• InChiKey: NPIWHZMLHSZJRN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chloroglycyl-DL-methioninatopalladium(II) monohydrate 、 胞嘧啶 以 水 为溶剂， 以70-80的产率得到glycyl-DL-methioninatocytosinepalladium(II)
  参考文献：
  名称：

  Crystal and molecular structure of chloroglycyl-dl-methioninatopalladium(II) monohydrate and its interaction with guanosine, cytidine and cytosine

  摘要：

  The crystal and molecular structure of the parent complex, chloroglycol-DL-methionatopalladium(II) monohydrate has been determined by X-ray diffraction analysis. Palladium has a square planar disposition in the complex and the deprotonated peptide moiety acts as a terdentate ligand and binds through N, O and S. The fourth coordination position on the metal ion is occupied by the chloride ion. The structure involves an extensive network of hydrogen bonds. Mixed ligand complexes of chloroglycl-DL-methionatopalladium(II) monohydrate with guanosine, cytosine and cytidine were synthesized and characterized by elemental analysis, conductivity measurements. IR and H-1 NMR spectral studies. In the case of guanosine, the metal coordinating site is N(7) whereas in cytosine and cytidine it is N(3).

  DOI：

  10.1016/s0277-5387(00)83324-0
• 作为产物：
  描述：

  potassium tetrachloropalladate(II) 、 甘氨酰-DL-甲硫氨酸 以 水 为溶剂， 生成 chloroglycyl-DL-methioninatopalladium(II) monohydrate
  参考文献：
  名称：

  Crystal and molecular structure of chloroglycyl-dl-methioninatopalladium(II) monohydrate and its interaction with guanosine, cytidine and cytosine

  摘要：

  The crystal and molecular structure of the parent complex, chloroglycol-DL-methionatopalladium(II) monohydrate has been determined by X-ray diffraction analysis. Palladium has a square planar disposition in the complex and the deprotonated peptide moiety acts as a terdentate ligand and binds through N, O and S. The fourth coordination position on the metal ion is occupied by the chloride ion. The structure involves an extensive network of hydrogen bonds. Mixed ligand complexes of chloroglycl-DL-methionatopalladium(II) monohydrate with guanosine, cytosine and cytidine were synthesized and characterized by elemental analysis, conductivity measurements. IR and H-1 NMR spectral studies. In the case of guanosine, the metal coordinating site is N(7) whereas in cytosine and cytidine it is N(3).

  DOI：

  10.1016/s0277-5387(00)83324-0