[Mn(NO)(CN)2(o-anisidine)2(H2O)] | 191469-79-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: [Mn(NO)(CN)2(o-anisidine)2(H2O)]
• CAS: 191469-79-1
• 化学式: C₁₆H₂₀MnN₅O₄
• 分子量: 401.304
• InChiKey: DJAKMHUAYJYZMB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  pentacyanonitrosylmanganate(I) anion 、 邻甲氧基苯胺 在 CH₃COOH 作用下， 以 溶剂黄146 为溶剂， 以55%的产率得到[Mn(NO)(CN)2(o-anisidine)2(H2O)]
  参考文献：
  名称：

  Metal Cyanonitrosyl Complexes: Synthesis, Magnetic, Thermal and Spectral Studies of Some Novel Mixed-Ligand Cyanonitrosyl {MnNO} Complexes of Manganese(I) with Potentially Mono₋and Bidentate Aniline Derivatives

  摘要：

  Novel mixed-ligand cyanonitrosyl {MnNO}(6) complexes of manganese(I), formed by the interaction of pentacyanonitrosyl-manganate(I) anion, [Mn(NO)(CN)(5)](3-), with potentially bidentate aniline derivatives, viz., o-phenylenediamine (o-PDA, I), m-phenylenediamine (m-PDA, II), and potentially mondentate aniline derivatives, o-anisidine (o-ANS, III), m-anisidine (m-ANS, IV), p-anisidine (o-ANS, V), o-phenetidine (o-PD, VI) ard m-phenetidine (m-PD, VII), are described. The resulting mixed-ligand complexes, which have been characterized by analytical data, electrical conductances, magnetic measurements, electronic spectra, thermogravimetric analyses and infrared spectral studies, have the compositions [Mn(NO)(CN)(2)(o-PDA)(H2O)], [Mn(NO)(CN)(2)(m-PDA)(H2O)(2)] or [Mn(NO)(CN)(2)(L)(2)(H2O)] (where L = III, IV, V, VI or VII). Suitable octahedral structures have been proposed for the complexes. Mangancse(I) has a low-spin {MnNO}(6) electron configuration in these complexes.

  DOI：

  10.1080/00945719708000216