[Zn(IAA)2(phen)] | 1330556-04-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: [Zn(IAA)2(phen)]
• 英文别名: [Zn(IAA)₂(phen)]
• CAS: 1330556-04-1
• 化学式: C₃₂H₂₄N₄O₄Zn
• 分子量: 593.957
• InChiKey: DIBTWBFTNHRVDH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 3-吲哚乙酸 、 zinc(II) acetate dihydrate 以 甲醇 为溶剂， 反应 2.0h， 以67.8%的产率得到[Zn(IAA)2(phen)]
  参考文献：
  名称：

  Synthesis, structure, fluorescence spectra study of two kinds of coordination supramolecular zinc compounds

  摘要：

  Two novel compounds [Zn(IAA)(2)(phen) (HIAA = indole-3-acetic acid, phen = 1,10-phenanthroline) (1) and [Zn(IAA)(2)(4,4 '-bipy)](4,4 '-bipy = 4,4 '-bipyridine) (2) were synthesized by the reaction of Zn(Ac)(2)center dot 2H(2)O or Zn(SO4)center dot 4H(2)0 as a metal source, HIAA as the first ligand and phen or 4,4 '-bipy as the second ligand in the system of methanol or the mixed solution of methanol and water at room temperature. They were characterized by elemental analysis, IR spectroscopy, UV-vis spectra and single-crystal X-ray diffraction. Structural analysis shows that the center metal Zn(II) for the compound I is four-coordinated, displaying a distorted tetrahedron; the metal center coordinated model for compound 2 is similar to that of 1, in which the structural unit of Zn(IAA)(2) was connected by bridging the 4, 4 '- bipy ligand to form an infinite 1D chain. In the packing of the compounds, there are some hydrogen bonding interactions and by the hydrogen bonding, 1D and 2D supramolecular structures were formed. Additional, we have studied the fluorescent properties of the two compounds. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2014.02.034