1-(9-ethyl-9H-carbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione | 1123732-11-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 1-(9-ethyl-9H-carbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione
• 英文别名: HECTFBD；4,4,4-trifluoro-1-(9-ethyl-9H-carbazol-3-yl)butane-1,3-dione；ECTFBD；1-(9-Ethylcarbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione
• CAS: 1123732-11-5
• 化学式: C₁₈H₁₄F₃NO₂
• 分子量: 333.31
• InChiKey: YJIWDCCMWDTIEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.52
• 重原子数：
  24.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  39.07
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  1-(9-ethyl-9H-carbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione 、 zinc(II) acetate dihydrate 在 sodium hydroxide 作用下， 反应 0.25h， 以85%的产率得到Zn(ECTFBD)₂
  参考文献：
  名称：

  Blue electroluminescence of a novel Zn2+–β-diketone complex with a carbazole moiety

  摘要：

  In this letter, a novel zinc complex of Zn(ECTFBD)(2) was synthesized by an environment-friendly grinding technique in high yield. Its structure was confirmed by H-1 NMR, MS and EA. HECTFBD is 1-(9-ethyl-9H-carbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione. Zn(ECTFBD)(2)-based light-emitting devices were fabricated. The architecture of the devices was ITO/PEDOT (40 nm)/100 wt% PVK: 40 wt% OXD-7: x wt% Zn(ECTFBD)(2) (85 nm)/CsF (1.5 nm)/Al (100 nm), where x = 1, 5, and 10 (relative to the mass of PVK and OXD-7). The three devices displayed blue emissions with peaks at 450, 458, and 460 nm, respectively. A maximum luminous efficiency of 0.86 cd/A and a luminance of 228 cd/m(2) were achieved by the I wt% doped device. So, we demonstrated further that Zn2+-beta-diketone complexes can be effectively severed as a class of new electroluminescent materials. In addition, the thermal stability of Zn(ECTFBD)(2) was tested and the UV-vis and photoluminescent behaviors of Zn(ECTFBD)(2) in CH2Cl2 were investigated. (C) 2013 Jian Liu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2013.09.008

文献信息

• Temporal thermal sensing and related methods
  申请人：C2Sense, Inc.

  公开号：US11513118B2

  公开（公告）日：2022-11-29

  Embodiments described herein generally relate to: sensing and/or authentication using luminescence imaging; diagnostic assays, systems, and related methods; temporal thermal sensing and related methods; and/or to emissive species, such as those excitable by white light, and related systems and methods.

  本文描述的实施方案一般涉及：使用发光成像进行传感和/或认证；诊断测定、系统和相关方法；时间热传感和相关方法；和/或发射物种，例如可被白光激发的物种，以及相关系统和方法。
• Effect of Different Alkyl Groups at the N-Position on the Luminescence of Carbazole-Based β-Diketonate Europium(III) Complexes
  作者：Pei He、Huihui Wang、Shenggui Liu、Jianxin Shi、Gang Wang、Menglian Gong

  DOI：10.1021/jp908416q

  日期：2009.11.19

  A series of carbazole-based beta-diketone derivatives and their europium(III) ternary complexes Eu(N-Cx)(3)phen were designed and synthesized, where N-Cx denotes carbazole-based beta-diketonates with different alkyl substituents at N-position of the carbazole ring and phen is 1,10-phenethroline. Thermogravimetric analysis (TGA) shows that the decomposition temperature of the complexes is over 360 degrees C. UV-visible absorption spectroscopy, photoluminescence (PL), and the luminescence quantum yield of the Eu(III) complexes were measured and compared with each other, and the effect of different substituted-alkyls at N-position in the carbazole ring on the photoluminescence was discussed in details, indicating there exists a competition between the absorption capacity and the energy transfer efficiency for the complexes when the structure of the substituted-alkyls changes. The triplet state energy levels of the beta-diketonate ligands in the complexes are higher than that of the lowest excited level of Eu3+ ion, D-5(0), so the photoluminescence mechanism of the Eu(HI) complexes was proposed as a ligand-sensitized luminescence process. Red LEDs were fabricated by precoating the complexes onto 395 nm emitting InGaN chips. All the results show that this series of Eu(III) complexes is a promising candidate as a red component in fabrication of NUV-based white LEDs.
• An Efficient Europium(III) Organic Complex as Red Phosphor Applied in LED
  作者：Pei He、Huihui Wang、Shenggui Liu、Wei Hu、Jianxin Shi、Gang Wang、Menglian Gong

  DOI：10.1149/1.3042206

  日期：——

  An efficient red-emitting europium(III) organic complex Eu(ECTFBD)(3)phen was designed and synthesized, where ECTFBD was 1-(9-ethyl-9H-carbazol-3-yl)-4,4,4-trifluorobutane-1,3-dione and phen was 1,10-phenanthroline. Eu(ECTFBD)(3)phen exhibits a high thermal stability and excellent photoluminescence properties. The photoluminescence mechanism of the complex was proposed as a ligand-sensitized luminescence process (antenna effect). A bright red light-emitting diode (LED) was fabricated by coating the complex phosphor onto an similar to 395 nm-emitting InGaN chip, whose CIE chromaticity coordinates (x=0.65, y=0.320) are close to the National Television Standard Committee standard values for red. All the results indicate that Eu(ECTFBD)(3)phen is a good candidate as a red component in the fabrication of white LEDs with a high color-rendering index.
• LUMINESCENCE IMAGING FOR SENSING
  申请人：C2Sense, Inc.

  公开号：EP4045898A1

  公开（公告）日：2022-08-24
• TEMPORAL THERMAL SENSING AND RELATED METHODS
  申请人：C2Sense, Inc.

  公开号：US20210116378A1

  公开（公告）日：2021-04-22

  Embodiments described herein generally relate to: sensing and/or authentication using luminescence imaging; diagnostic assays, systems, and related methods; temporal thermal sensing and related methods; and/or to emissive species, such as those excitable by white light, and related systems and methods.