[(2,6-bis((2,6-dimethylphenylimino)methyl)pyridine)Cd(S2CNEt2)][Cl] | 455894-22-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [(2,6-bis((2,6-dimethylphenylimino)methyl)pyridine)Cd(S2CNEt2)][Cl]
• CAS: 455894-22-1
• 化学式: C₂₈H₃₃CdN₄S₂*Cl
• 分子量: 637.592
• InChiKey: OUZXXAUSNHVQQU-YMCUJNOTSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (2,6-bis[(2,6-dimethylphenylimino)methyl]pyridine)CdCl2 、 sodium N,N-diethyldithiocarbamate 以 四氢呋喃 为溶剂， 以70%的产率得到[(2,6-bis((2,6-dimethylphenylimino)methyl)pyridine)Cd(S2CNEt2)][Cl]
  参考文献：
  名称：

  Mixed-ligand complexes of cadmium(II) containing bulky polydentate nitrogen-based ligands

  摘要：

  The reaction of equimolar amounts of CdCl2, Tl[H2B(3-Bu(1)pz)(2)] (pz = pyrazolyl ring) and Na[Et2NCS2] yields [H2B(3-Bu(1)pz)(2)]Cd(S2CNEt2) (1) and a similar reaction using Tl[HB(3-Bu(1)pz)(3)] yields [HB(3-Bu(1)pz)(3)]Cd(S2CNEt2) (2). The solid state structure of [HB(3-Bu(1)pz)(3)]Cd(S2CNEt2) shows the arrangement of the donor atoms is a distorted trigonal bipyramid, an unusual geometry for a molecule containing a tridentate [HB(3-Bu(1)pz)(3)](-) ligand. Mixing CdCl2 with 2 equiv. of MeLi yields the Me2Cd intermediate that reacts with Tl[HB(3-Phpz)(3)] to yield [HB(3-Phpz)(3)]CdCH3 (3). Compound 3 reacts with thiotoluene to yield [HB(3-Phpz)(3)]CdS(p-C6H4CH3) (4) and mercaptopyridine to yield [HB(3-Phpz)(3)]Cd(SNC6H4) (5). The neutral 2,6-bis(2,6-dimethylphenylimino)pyridine ligand (pydim) reacts with CdCl2 in equimolar amounts to yield the adduct (pydim)CdCl2 (6). The cadmium(II) is in a five-coordinate arrangement that is best described as a distorted trigonal bipyramid. The three nitrogen atoms of the planar pyridine ligand occupy an equatorial and both axial sites, but the intrinsic bite angle of the ligand forces a significant distortion in the axial bond angle. Compound 6 reacts with an equimolar amount of Na[Et2NCS2] to yield [(pydim)Cd(S2CNEt2)][Cl] (7). The reaction of equimolar amounts of pydimMe(2) and Cd(NO3)(2) yields (pydimMe(2))Cd(NO3)(2) (8). In the structure of this complex, one nitrate ligand is bidentate and the other monodentate. If the bidentate ligand is considered as occupying one site of a polyhedron, the structure of 8 can be considered as a trigonal bipyramid, very similar to that of 6. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00735-1